Pd-Co3[Co(CN)6]2 hybrid nanoparticles: Preparation, characterization, and challenge for the Suzuki-Miyaura coupling of aryl chlorides under mild conditions

Ren Li; Ran Li; Changlai Wang; Lei Gao; Qianwang Chen

doi:10.1039/c5dt03631c

Pd-Co₃[Co(CN)₆]₂ hybrid nanoparticles: Preparation, characterization, and challenge for the Suzuki-Miyaura coupling of aryl chlorides under mild conditions

Ren Li, Ran Li, Changlai Wang, Lei Gao, Qianwang Chen

Research output: Contribution to journal › Article › peer-review

Abstract

Because of their abundance and low cost, organo chlorides are the most desirable substrates from the industrial point of view in Suzuki-Miyaura cross-coupling reactions. However, catalytic application of Pd nanoparticles (NPs) for Suzuki coupling of aryl chlorides is still a challenge. Here, we design a novel catalyst by combining Pd NPs with Co₃[Co(CN)₆]₂ nanocrystals for Suzuki-Miyaura coupling of aryl chlorides. This nanocatalyst demonstrated good activity (yield 86.2% at 80 °C), high TOF, great stability, easy separation, excellent reusability (initial rates were not reduced after five cycles) and low cost in Suzuki reactions.

Original language	English
Pages (from-to)	539-544
Number of pages	6
Journal	Dalton Transactions
Volume	45
Issue number	2
DOIs	https://doi.org/10.1039/c5dt03631c
Publication status	Published - 2015

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10.1039/c5dt03631c

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abstract = "Because of their abundance and low cost, organo chlorides are the most desirable substrates from the industrial point of view in Suzuki-Miyaura cross-coupling reactions. However, catalytic application of Pd nanoparticles (NPs) for Suzuki coupling of aryl chlorides is still a challenge. Here, we design a novel catalyst by combining Pd NPs with Co3[Co(CN)6]2 nanocrystals for Suzuki-Miyaura coupling of aryl chlorides. This nanocatalyst demonstrated good activity (yield 86.2% at 80 °C), high TOF, great stability, easy separation, excellent reusability (initial rates were not reduced after five cycles) and low cost in Suzuki reactions.",

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year = "2015",

doi = "10.1039/c5dt03631c",

language = "English",

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publisher = "Royal Society of Chemistry",

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T1 - Pd-Co3[Co(CN)6]2 hybrid nanoparticles

T2 - Preparation, characterization, and challenge for the Suzuki-Miyaura coupling of aryl chlorides under mild conditions

AU - Li, Ren

AU - Li, Ran

AU - Wang, Changlai

AU - Gao, Lei

AU - Chen, Qianwang

PY - 2015

Y1 - 2015

N2 - Because of their abundance and low cost, organo chlorides are the most desirable substrates from the industrial point of view in Suzuki-Miyaura cross-coupling reactions. However, catalytic application of Pd nanoparticles (NPs) for Suzuki coupling of aryl chlorides is still a challenge. Here, we design a novel catalyst by combining Pd NPs with Co3[Co(CN)6]2 nanocrystals for Suzuki-Miyaura coupling of aryl chlorides. This nanocatalyst demonstrated good activity (yield 86.2% at 80 °C), high TOF, great stability, easy separation, excellent reusability (initial rates were not reduced after five cycles) and low cost in Suzuki reactions.

AB - Because of their abundance and low cost, organo chlorides are the most desirable substrates from the industrial point of view in Suzuki-Miyaura cross-coupling reactions. However, catalytic application of Pd nanoparticles (NPs) for Suzuki coupling of aryl chlorides is still a challenge. Here, we design a novel catalyst by combining Pd NPs with Co3[Co(CN)6]2 nanocrystals for Suzuki-Miyaura coupling of aryl chlorides. This nanocatalyst demonstrated good activity (yield 86.2% at 80 °C), high TOF, great stability, easy separation, excellent reusability (initial rates were not reduced after five cycles) and low cost in Suzuki reactions.

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DO - 10.1039/c5dt03631c

M3 - Article

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SN - 1477-9226

VL - 45

SP - 539

EP - 544

JO - Dalton Transactions

JF - Dalton Transactions

IS - 2

ER -

Pd-Co₃[Co(CN)₆]₂ hybrid nanoparticles: Preparation, characterization, and challenge for the Suzuki-Miyaura coupling of aryl chlorides under mild conditions

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