Oxidation of allylselenides with the sharpless AD-reagents

A. Krief; C. Colaux; W. Dumont

doi:10.1016/S0040-4039(97)00596-0

Oxidation of allylselenides with the sharpless AD-reagents

A. Krief, C. Colaux, W. Dumont

Unit of organic chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Allylselenides are efficiently oxidized by AD-mix reagents. Oxidation takes chemoselectively place on the selenium atom of allylselenides bearing a methylseleno or a phenylseleno moiety, but chemoselectively occurs on the C,C double bond of the corresponding o-nitrophenyl derivatives.

Original language	English
Pages (from-to)	3315-3318
Number of pages	4
Journal	Tetrahedron Letters
Volume	38
Issue number	18
DOIs	https://doi.org/10.1016/S0040-4039(97)00596-0
Publication status	Published - 5 May 1997

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title = "Oxidation of allylselenides with the sharpless AD-reagents",

abstract = "Allylselenides are efficiently oxidized by AD-mix reagents. Oxidation takes chemoselectively place on the selenium atom of allylselenides bearing a methylseleno or a phenylseleno moiety, but chemoselectively occurs on the C,C double bond of the corresponding o-nitrophenyl derivatives.",

author = "A. Krief and C. Colaux and W. Dumont",

year = "1997",

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T1 - Oxidation of allylselenides with the sharpless AD-reagents

AU - Krief, A.

AU - Colaux, C.

AU - Dumont, W.

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Y1 - 1997/5/5

N2 - Allylselenides are efficiently oxidized by AD-mix reagents. Oxidation takes chemoselectively place on the selenium atom of allylselenides bearing a methylseleno or a phenylseleno moiety, but chemoselectively occurs on the C,C double bond of the corresponding o-nitrophenyl derivatives.

AB - Allylselenides are efficiently oxidized by AD-mix reagents. Oxidation takes chemoselectively place on the selenium atom of allylselenides bearing a methylseleno or a phenylseleno moiety, but chemoselectively occurs on the C,C double bond of the corresponding o-nitrophenyl derivatives.

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DO - 10.1016/S0040-4039(97)00596-0

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EP - 3318

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 18

ER -

Oxidation of allylselenides with the sharpless AD-reagents

Abstract

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