Orientation of thiophenol adsorbed on silver determined by nonlinear vibrational spectroscopy of the carbon skeleton

A.A. Mani, Z.D. Schultz, Y. Caudano, B. Champagne, C. Humbert, L. Dreesen, A.A. Gewirth, J.O. White, P.A. Thiry, A. Peremans

Research output: Contribution to journalArticle

Abstract

The orientation of thiophenol adsorbed on silver is determined by comparing ab initio calculated and experimental sum-frequency generation (SFG) spectra measured between 9 and 20 μm using a tandem KTP/ CdSe optical parametric oscillator. The molecule S-C bond is tilted ∼37° from the surface normal with the aromatic ring plane perpendicular to the surface.
Original languageEnglish
Pages (from-to)16135-16138
Number of pages4
JournalJournal of physical chemistry B
Volume108
Issue number41
DOIs
Publication statusPublished - 14 Oct 2004

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Vibrational spectroscopy
Silver
Optical parametric oscillators
Carbon
Molecules

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Mani, A.A. ; Schultz, Z.D. ; Caudano, Y. ; Champagne, B. ; Humbert, C. ; Dreesen, L. ; Gewirth, A.A. ; White, J.O. ; Thiry, P.A. ; Peremans, A. / Orientation of thiophenol adsorbed on silver determined by nonlinear vibrational spectroscopy of the carbon skeleton. In: Journal of physical chemistry B. 2004 ; Vol. 108, No. 41. pp. 16135-16138.
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Orientation of thiophenol adsorbed on silver determined by nonlinear vibrational spectroscopy of the carbon skeleton. / Mani, A.A.; Schultz, Z.D.; Caudano, Y.; Champagne, B.; Humbert, C.; Dreesen, L.; Gewirth, A.A.; White, J.O.; Thiry, P.A.; Peremans, A.

In: Journal of physical chemistry B, Vol. 108, No. 41, 14.10.2004, p. 16135-16138.

Research output: Contribution to journalArticle

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AU - Humbert, C.

AU - Dreesen, L.

AU - Gewirth, A.A.

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AU - Thiry, P.A.

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