Orientation of thiophenol adsorbed on silver determined by nonlinear vibrational spectroscopy of the carbon skeleton

A.A. Mani; Z.D. Schultz; Y. Caudano; B. Champagne; C. Humbert; L. Dreesen; A.A. Gewirth; J.O. White; P.A. Thiry; A. Peremans

doi:10.1021/jp037661d

Orientation of thiophenol adsorbed on silver determined by nonlinear vibrational spectroscopy of the carbon skeleton

A.A. Mani, Z.D. Schultz, Y. Caudano, B. Champagne, C. Humbert, L. Dreesen, A.A. Gewirth, J.O. White, P.A. Thiry, A. Peremans

Research output: Contribution to journal › Article › peer-review

Abstract

The orientation of thiophenol adsorbed on silver is determined by comparing ab initio calculated and experimental sum-frequency generation (SFG) spectra measured between 9 and 20 μm using a tandem KTP/ CdSe optical parametric oscillator. The molecule S-C bond is tilted ∼37° from the surface normal with the aromatic ring plane perpendicular to the surface.

Original language	English
Pages (from-to)	16135-16138
Number of pages	4
Journal	Journal of physical chemistry B
Volume	108
Issue number	41
DOIs	https://doi.org/10.1021/jp037661d
Publication status	Published - 14 Oct 2004

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abstract = "The orientation of thiophenol adsorbed on silver is determined by comparing ab initio calculated and experimental sum-frequency generation (SFG) spectra measured between 9 and 20 μm using a tandem KTP/ CdSe optical parametric oscillator. The molecule S-C bond is tilted ∼37° from the surface normal with the aromatic ring plane perpendicular to the surface.",

author = "A.A. Mani and Z.D. Schultz and Y. Caudano and B. Champagne and C. Humbert and L. Dreesen and A.A. Gewirth and J.O. White and P.A. Thiry and A. Peremans",

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T1 - Orientation of thiophenol adsorbed on silver determined by nonlinear vibrational spectroscopy of the carbon skeleton

AU - Mani, A.A.

AU - Schultz, Z.D.

AU - Caudano, Y.

AU - Champagne, B.

AU - Humbert, C.

AU - Dreesen, L.

AU - Gewirth, A.A.

AU - White, J.O.

AU - Thiry, P.A.

AU - Peremans, A.

PY - 2004/10/14

Y1 - 2004/10/14

N2 - The orientation of thiophenol adsorbed on silver is determined by comparing ab initio calculated and experimental sum-frequency generation (SFG) spectra measured between 9 and 20 μm using a tandem KTP/ CdSe optical parametric oscillator. The molecule S-C bond is tilted ∼37° from the surface normal with the aromatic ring plane perpendicular to the surface.

AB - The orientation of thiophenol adsorbed on silver is determined by comparing ab initio calculated and experimental sum-frequency generation (SFG) spectra measured between 9 and 20 μm using a tandem KTP/ CdSe optical parametric oscillator. The molecule S-C bond is tilted ∼37° from the surface normal with the aromatic ring plane perpendicular to the surface.

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U2 - 10.1021/jp037661d

DO - 10.1021/jp037661d

M3 - Article

AN - SCOPUS:7044223088

SN - 1520-6106

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SP - 16135

EP - 16138

JO - Journal of physical chemistry B

JF - Journal of physical chemistry B

IS - 41

ER -

Orientation of thiophenol adsorbed on silver determined by nonlinear vibrational spectroscopy of the carbon skeleton

Abstract

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