Organic-bridged faujasite X zeolites ZOF-X

Bao Lian Su, K. Vause, M. Roussel, L. Shi, X. D. Zou, E. Leonova, M. Edén

Research output: Contribution in Book/Catalog/Report/Conference proceedingChapter

Abstract

Highly thermally stable Faujasite X zeolites with organic-bridged frameworks (ZOF-X) have been for the first time synthesized, in which oxygen atoms in the zeolite frameworks are partially superseded by methylene groups using methylene-bridged bis[triethoxysilyl]methane (BTESM) as a unique silicon source. The presence and the amount of the methylene groups within the framework have been revealed and determined by a series of techniques such as 29Si and 13C MAS NMR, XRD, SEM-EDS, FTIR, TG, N2 adsorption and elemental analysis. The present study showed that the synthesis of ZOF-X materials is quite sensitive to many parameters such as the crystallization and the ageing conditions and finally the batch compositions.

Original languageEnglish
Title of host publicationFrom Zeolites to Porous MOF Materials
Subtitle of host publicationThe 40th Anniversary of International Zeolite Conference
EditorsRuren Xu, Zi Gao, Jiesheng Chen, Wenfu Yan
PublisherElsevier Inc.
Pages539-545
Number of pages7
EditionA
ISBN (Print)0444530681, 9780444530684
DOIs
Publication statusPublished - 1 Jan 2007

Publication series

NameStudies in Surface Science and Catalysis
NumberA
Volume170
ISSN (Print)0167-2991

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