Abstract
The intimate mechanism of the one pot synthesis of chrysanthemic esters from methyl 4-oxo-butenoate and phosphorus ylide is disclosed. The first equivalent of ylide reacts selectively on the aldehyde function and the cyclopropanation occurs on the preformed betaine prior to its decomposition.
Original language | English |
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Pages (from-to) | 1511-1514 |
Number of pages | 4 |
Journal | Tetrahedron Letters |
Volume | 20 |
Issue number | 17 |
Publication status | Published - 1 Jan 1979 |