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Abstract
Using a dual beam diode-laser spectrometer, we have studied with accuracy the N2-shift coefficients in the P-branch of the υ3 band of methane. The experiments were performed at room temperature for 16 lines in the spectral range 2906-2948 cm-1 with J values between 7 and 11. Each line was recorded at four different nitrogen pressures ranging from 17 to 302 mbar. The collisional shifts were obtained by fitting to the experimental lineshape a Rautian-Sobel'Man profile that takes into account the Dicke narrowing. The shift coefficients were determined using a procedure where a non perturbed line of pure CH4 was simultaneously recorded with N2-shifted transitions. Finally, we give a comparison with previous published results.
Translated title of the contribution | Coefficients de déplacement dus à l'azote dans la bande ν3 du 12CH4 à température ambiante |
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Original language | English |
Pages (from-to) | 7-10 |
Journal | Journal of molecular spectroscopy |
Volume | 298 |
DOIs | |
Publication status | Published - Apr 2014 |
Keywords
- Methane
- Diode-laser spectroscopy
- Line shifts
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Dive into the research topics of 'N2-shift coefficients in the ν3 band of 12CH4 at room temperature'. Together they form a unique fingerprint.Projects
- 1 Finished
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Study by diode-laser spectroscopy of profiles and collisional parameters of infrared absorption lines of methane at low and high temperatures
Vispoel, B. (PI) & Lepere, M. (CoI)
1/01/13 → 16/11/16
Project: PHD
Equipment
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Optics, Lasers and spectroscopy
Lepere, M. (Manager)
Technological Platform Optics, Lasers and spectroscopyFacility/equipment: Technological Platform