TY - JOUR
T1 - N2-broadening coefficients in the ν2 and ν4 bands of PH3 at low temperature
AU - Bouanich, J.-P.
AU - Blanquet, G.
N1 - Copyright 2008 Elsevier B.V., All rights reserved.
PY - 2007/2/1
Y1 - 2007/2/1
N2 - N-broadening coefficients have been measured for 41 transitions of PH at -100 °C in the R branch of the ν band and the P, P, and P branches of the ν band, using a tunable diode-laser spectrometer. The recorded lines with J values ranging from 1 to 13 and K from 0 to 10 are located between 1026 and 1093 cm. The collisional widths are determined by fitting each spectral line with a Voigt profile, a Rautian profile, and a speed-dependent Rautian profile. The latter models provide larger broadening coefficients than the Voigt model. These coefficients have also been calculated on the basis of a semiclassical model of interacting linear molecules by considering an atom-atom Lennard-Jones potential in addition to the electrostatic contributions. By comparing broadening coefficients at room and low temperatures, the temperature dependence of these broadenings has been determined both experimentally and theoretically.
AB - N-broadening coefficients have been measured for 41 transitions of PH at -100 °C in the R branch of the ν band and the P, P, and P branches of the ν band, using a tunable diode-laser spectrometer. The recorded lines with J values ranging from 1 to 13 and K from 0 to 10 are located between 1026 and 1093 cm. The collisional widths are determined by fitting each spectral line with a Voigt profile, a Rautian profile, and a speed-dependent Rautian profile. The latter models provide larger broadening coefficients than the Voigt model. These coefficients have also been calculated on the basis of a semiclassical model of interacting linear molecules by considering an atom-atom Lennard-Jones potential in addition to the electrostatic contributions. By comparing broadening coefficients at room and low temperatures, the temperature dependence of these broadenings has been determined both experimentally and theoretically.
UR - http://www.scopus.com/inward/record.url?scp=33846923334&partnerID=8YFLogxK
U2 - 10.1016/j.jms.2006.12.006
DO - 10.1016/j.jms.2006.12.006
M3 - Article
AN - SCOPUS:33846923334
SN - 0022-2852
VL - 241
SP - 186
EP - 191
JO - Journal of molecular spectroscopy
JF - Journal of molecular spectroscopy
IS - 2
ER -