Novel synthetic route to aryl alkanes from aromatic aldehydes and ketones. Novel geminal dialkylation of the carbonyl group of aromatic aldehydes and ketones

A. Krief; M. Clarembeau; Ph. Barbeaux

doi:10.1039/C39860000457

Novel synthetic route to aryl alkanes from aromatic aldehydes and ketones. Novel geminal dialkylation of the carbonyl group of aromatic aldehydes and ketones

A. Krief, M. Clarembeau, Ph. Barbeaux

Research output: Contribution to journal › Article › peer-review

Abstract

Benzyl-lithiums, readily available from benzyl methyl selenides and alkyl-lithiums, are efficiently alkylated; this reaction allows the geminal dialkylation of the carbonyl groups of aromatic aldehydes and ketones and the geminal aryl-alkylation of aliphatic analogues.

Original language	English
Pages (from-to)	457-458
Number of pages	2
Journal	Journal of the Chemical society. Chemical communications
Issue number	6
DOIs	https://doi.org/10.1039/C39860000457
Publication status	Published - 1 Jan 1986

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title = "Novel synthetic route to aryl alkanes from aromatic aldehydes and ketones. Novel geminal dialkylation of the carbonyl group of aromatic aldehydes and ketones",

abstract = "Benzyl-lithiums, readily available from benzyl methyl selenides and alkyl-lithiums, are efficiently alkylated; this reaction allows the geminal dialkylation of the carbonyl groups of aromatic aldehydes and ketones and the geminal aryl-alkylation of aliphatic analogues.",

author = "A. Krief and M. Clarembeau and Ph. Barbeaux",

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AU - Clarembeau, M.

AU - Barbeaux, Ph.

PY - 1986/1/1

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AB - Benzyl-lithiums, readily available from benzyl methyl selenides and alkyl-lithiums, are efficiently alkylated; this reaction allows the geminal dialkylation of the carbonyl groups of aromatic aldehydes and ketones and the geminal aryl-alkylation of aliphatic analogues.

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Novel synthetic route to aryl alkanes from aromatic aldehydes and ketones. Novel geminal dialkylation of the carbonyl group of aromatic aldehydes and ketones

Abstract

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