Nonlinear optical molecular switches as selective cation sensors

B. Champagne, A. Plaquet, J.-L. Pozzo, V. Rodriguez, F. Castet

    Research output: Contribution to journalArticlepeer-review

    Abstract

    This work demonstrates that the recognition of cations by molecular switches can give rise to large contrasts of the second-order nonlinear optical (NLO) properties, which can therefore be used as a powerful and multi-usage detection tool. The proof of concept is given by evidencing, by means of ab initio calculations, the ability of spiropyran/merocyanine systems to selectively detect alkali, alkaline earth, and transition-metal cations.
    Original languageEnglish
    Pages (from-to)8101-8103
    Number of pages3
    JournalJournal of the American Chemical Society
    Volume134
    Issue number19
    DOIs
    Publication statusPublished - 16 May 2012

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