Modulating electronic interactions between closely spaced complementary p surfaces with different outcomes: Regio- and diastereomerically pure subphthalocyanine-C60 tris adducts

David Gonzalez-Rodriguez, Esther Carbonell Llopis, Dirk M. Guldi, Tomas Torres

Research output: Contribution to journalArticlepeer-review

Abstract

Tightly coupled, regio- and diastereomerically pure subphthalocyanine- C60 dyads (see spacefilling depiction; B orange, C light blue, H gray, N blue, O red), tethered by means of a trisaddition reaction, can follow different mechanisms on photoexcitation (electron transfer or energy transfer), depending on the spacing between the two complementary π surfaces.

Original languageEnglish
Pages (from-to)8032-8036
Number of pages5
JournalAngewandte Chemie International Edition
Volume48
Issue number43
DOIs
Publication statusPublished - 12 Oct 2009
Externally publishedYes

Keywords

  • π interactions
  • Electron transfer
  • Energy transfer
  • Fullerenes
  • Subphthalocyanines

Fingerprint

Dive into the research topics of 'Modulating electronic interactions between closely spaced complementary p surfaces with different outcomes: Regio- and diastereomerically pure subphthalocyanine-C60 tris adducts'. Together they form a unique fingerprint.

Cite this