Isomerisation of 2,2-dimethyl dimedone to (D,L) cis-chrysanthemic acid

A. Krief; G. Lorvelec; S. Jeanmart

doi:10.1016/S0040-4039(00)00542-6

Isomerisation of 2,2-dimethyl dimedone to (D,L) cis-chrysanthemic acid

A. Krief, G. Lorvelec, S. Jeanmart

Unit of organic chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

(D,L) cis-Chrysanthemic acid has been obtained in four steps from 2,2- dimethyl dimedone which involves Bamford-Stevens olefination and tandem cyclization-Grob fragmentation reactions. (C) 2000 Published by Elsevier Science Ltd.

Original language	English
Pages (from-to)	3871-3874
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
Issue number	20
DOIs	https://doi.org/10.1016/S0040-4039(00)00542-6
Publication status	Published - 21 May 2000

Keywords

1-3-elimination
diketone
cyclopropane
chrysanthemic acid
pyrethroid
Bamford-Stevens reaction
organic chemistry
grob fragmentation
chrysanthemum
dimethyldimedone
insecticide

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title = "Isomerisation of 2,2-dimethyl dimedone to (D,L) cis-chrysanthemic acid",

abstract = "(D,L) cis-Chrysanthemic acid has been obtained in four steps from 2,2- dimethyl dimedone which involves Bamford-Stevens olefination and tandem cyclization-Grob fragmentation reactions. (C) 2000 Published by Elsevier Science Ltd.",

keywords = " 1-3-elimination, diketone, cyclopropane, chrysanthemic acid, pyrethroid, Bamford-Stevens reaction, organic chemistry, grob fragmentation, chrysanthemum, dimethyldimedone, insecticide",

author = "A. Krief and G. Lorvelec and S. Jeanmart",

year = "2000",

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day = "21",

doi = "10.1016/S0040-4039(00)00542-6",

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journal = "Tetrahedron Letters",

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T1 - Isomerisation of 2,2-dimethyl dimedone to (D,L) cis-chrysanthemic acid

AU - Krief, A.

AU - Lorvelec, G.

AU - Jeanmart, S.

PY - 2000/5/21

Y1 - 2000/5/21

N2 - (D,L) cis-Chrysanthemic acid has been obtained in four steps from 2,2- dimethyl dimedone which involves Bamford-Stevens olefination and tandem cyclization-Grob fragmentation reactions. (C) 2000 Published by Elsevier Science Ltd.

AB - (D,L) cis-Chrysanthemic acid has been obtained in four steps from 2,2- dimethyl dimedone which involves Bamford-Stevens olefination and tandem cyclization-Grob fragmentation reactions. (C) 2000 Published by Elsevier Science Ltd.

KW - 1-3-elimination

KW - diketone

KW - cyclopropane

KW - chrysanthemic acid

KW - pyrethroid

KW - Bamford-Stevens reaction

KW - organic chemistry

KW - grob fragmentation

KW - chrysanthemum

KW - dimethyldimedone

KW - insecticide

UR - http://www.scopus.com/inward/record.url?scp=0034697536&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)00542-6

DO - 10.1016/S0040-4039(00)00542-6

M3 - Article

SN - 0040-4039

VL - 41

SP - 3871

EP - 3874

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 20

ER -

Isomerisation of 2,2-dimethyl dimedone to (D,L) cis-chrysanthemic acid

Abstract

Keywords

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