Intramolecular vibronic dynamics in molecular solids: C60

L. KJELDGAARD; T. KÄÄMBRE; J. SCHIESSLING; Ingrid Marenne; J.N. O'SHEA; J. SCHNADT; C.J. GLOVER; M. NAGASONO; D. NORDLUND; M.G. GARNIER; L. QIAN; J.-E. RUBENSSON; Petra Rudolf; N. MARTENSSON; J. NORDGREN; P.A. BRÜHWILER

doi:10.1103/PhysRevB.72.205414

Intramolecular vibronic dynamics in molecular solids: C₆₀

L. KJELDGAARD, T. KÄÄMBRE, J. SCHIESSLING, Ingrid Marenne, J.N. O'SHEA, J. SCHNADT, C.J. GLOVER, M. NAGASONO, D. NORDLUND, M.G. GARNIER, L. QIAN, J.-E. RUBENSSON, Petra Rudolf, N. MARTENSSON, J. NORDGREN, P.A. BRÜHWILER

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Abstract

Vibronic coupling in solid C60 has been investigated with a combination of resonant photoemission spectroscopy (RPES) and resonant inelastic x-ray scattering (RIXS). Excitation as a function of energy within the lowest unoccupied molecular orbital resonance yielded strong oscillations in intensity and dispersion in RPES, and a strong inelastic component in RIXS. Reconciling these two observations establishes that vibronic coupling in this core hole excitation leads to predominantly inelastic scattering and localization of the excited vibrations on the molecule on a femtosecond time scale. The coupling extends throughout the widths of the frontier valence bands.

Original language	English
Journal	Physical Review. B, Condensed Matter and Materials Physics
Volume	72
Issue number	20
DOIs	https://doi.org/10.1103/PhysRevB.72.205414
Publication status	Published - 2005

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10.1103/PhysRevB.72.205414

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KJELDGAARD, L., KÄÄMBRE, T., SCHIESSLING, J., Marenne, I., O'SHEA, J. N., SCHNADT, J., GLOVER, C. J., NAGASONO, M., NORDLUND, D., GARNIER, M. G., QIAN, L., RUBENSSON, J.-E., Rudolf, P., MARTENSSON, N., NORDGREN, J., & BRÜHWILER, P. A. (2005). Intramolecular vibronic dynamics in molecular solids: C₆₀. Physical Review. B, Condensed Matter and Materials Physics, 72(20). https://doi.org/10.1103/PhysRevB.72.205414

@article{15b00e25e33948519204a96cfd2a2d42,

title = "Intramolecular vibronic dynamics in molecular solids: C60",

abstract = "Vibronic coupling in solid C60 has been investigated with a combination of resonant photoemission spectroscopy (RPES) and resonant inelastic x-ray scattering (RIXS). Excitation as a function of energy within the lowest unoccupied molecular orbital resonance yielded strong oscillations in intensity and dispersion in RPES, and a strong inelastic component in RIXS. Reconciling these two observations establishes that vibronic coupling in this core hole excitation leads to predominantly inelastic scattering and localization of the excited vibrations on the molecule on a femtosecond time scale. The coupling extends throughout the widths of the frontier valence bands.",

author = "L. KJELDGAARD and T. K{\"A}{\"A}MBRE and J. SCHIESSLING and Ingrid Marenne and J.N. O'SHEA and J. SCHNADT and C.J. GLOVER and M. NAGASONO and D. NORDLUND and M.G. GARNIER and L. QIAN and J.-E. RUBENSSON and Petra Rudolf and N. MARTENSSON and J. NORDGREN and P.A. BR{\"U}HWILER",

year = "2005",

doi = "10.1103/PhysRevB.72.205414",

language = "English",

volume = "72",

journal = "Physical Review. B, Condensed Matter and Materials Physics",

issn = "1098-0121",

publisher = "American Institute of Physics Publising LLC",

number = "20",

}

KJELDGAARD, L, KÄÄMBRE, T, SCHIESSLING, J, Marenne, I, O'SHEA, JN, SCHNADT, J, GLOVER, CJ, NAGASONO, M, NORDLUND, D, GARNIER, MG, QIAN, L, RUBENSSON, J-E, Rudolf, P, MARTENSSON, N, NORDGREN, J & BRÜHWILER, PA 2005, 'Intramolecular vibronic dynamics in molecular solids: C₆₀', Physical Review. B, Condensed Matter and Materials Physics, vol. 72, no. 20. https://doi.org/10.1103/PhysRevB.72.205414

TY - JOUR

T1 - Intramolecular vibronic dynamics in molecular solids: C60

AU - KJELDGAARD, L.

AU - KÄÄMBRE, T.

AU - SCHIESSLING, J.

AU - Marenne, Ingrid

AU - O'SHEA, J.N.

AU - SCHNADT, J.

AU - GLOVER, C.J.

AU - NAGASONO, M.

AU - NORDLUND, D.

AU - GARNIER, M.G.

AU - QIAN, L.

AU - RUBENSSON, J.-E.

AU - Rudolf, Petra

AU - MARTENSSON, N.

AU - NORDGREN, J.

AU - BRÜHWILER, P.A.

PY - 2005

Y1 - 2005

N2 - Vibronic coupling in solid C60 has been investigated with a combination of resonant photoemission spectroscopy (RPES) and resonant inelastic x-ray scattering (RIXS). Excitation as a function of energy within the lowest unoccupied molecular orbital resonance yielded strong oscillations in intensity and dispersion in RPES, and a strong inelastic component in RIXS. Reconciling these two observations establishes that vibronic coupling in this core hole excitation leads to predominantly inelastic scattering and localization of the excited vibrations on the molecule on a femtosecond time scale. The coupling extends throughout the widths of the frontier valence bands.

AB - Vibronic coupling in solid C60 has been investigated with a combination of resonant photoemission spectroscopy (RPES) and resonant inelastic x-ray scattering (RIXS). Excitation as a function of energy within the lowest unoccupied molecular orbital resonance yielded strong oscillations in intensity and dispersion in RPES, and a strong inelastic component in RIXS. Reconciling these two observations establishes that vibronic coupling in this core hole excitation leads to predominantly inelastic scattering and localization of the excited vibrations on the molecule on a femtosecond time scale. The coupling extends throughout the widths of the frontier valence bands.

U2 - 10.1103/PhysRevB.72.205414

DO - 10.1103/PhysRevB.72.205414

M3 - Article

SN - 1098-0121

VL - 72

JO - Physical Review. B, Condensed Matter and Materials Physics

JF - Physical Review. B, Condensed Matter and Materials Physics

IS - 20

ER -

Intramolecular vibronic dynamics in molecular solids: C60

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Intramolecular vibronic dynamics in molecular solids: C₆₀