Hydrogen-broadening coefficients in the ν5 band of acetylene at low temperature

J.-P. Bouanich, J. Walrand, G. Blanquet

Research output: Contribution to journalArticle

Abstract

H-broadening coefficients have been measured for 29 lines of CH at 173.2 K in the P and R branches of the ν fundamental band near 13.7 μm, using a tunable diode-laser spectrometer. These lines were individually fitted with a Voigt and a Rautian profile in order to determine the collisional widths. The resulting broadening coefficients are compared with values calculated from a semiclassical theory performed by considering, in addition to electrostatic interactions, the atom-atom Lennard-Jones model. A satisfactory agreement is obtained but only for low and medium J values. By comparing broadening coefficients at 297 and 173.2 K from a simple power law, the temperature dependence of these broadenings has been determined both experimentally and theoretically.
Original languageEnglish
Pages (from-to)266-270
Number of pages5
JournalJournal of molecular spectroscopy
Volume216
Issue number2
DOIs
Publication statusPublished - 1 Jan 2002

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Acetylene
acetylene
Hydrogen
Atoms
hydrogen
coefficients
Coulomb interactions
Semiconductor lasers
Spectrometers
laser spectrometers
Temperature
atoms
diodes
methylidyne
electrostatics
temperature dependence
profiles
interactions

Cite this

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abstract = "H-broadening coefficients have been measured for 29 lines of CH at 173.2 K in the P and R branches of the ν fundamental band near 13.7 μm, using a tunable diode-laser spectrometer. These lines were individually fitted with a Voigt and a Rautian profile in order to determine the collisional widths. The resulting broadening coefficients are compared with values calculated from a semiclassical theory performed by considering, in addition to electrostatic interactions, the atom-atom Lennard-Jones model. A satisfactory agreement is obtained but only for low and medium J values. By comparing broadening coefficients at 297 and 173.2 K from a simple power law, the temperature dependence of these broadenings has been determined both experimentally and theoretically.",
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Hydrogen-broadening coefficients in the ν5 band of acetylene at low temperature. / Bouanich, J.-P.; Walrand, J.; Blanquet, G.

In: Journal of molecular spectroscopy, Vol. 216, No. 2, 01.01.2002, p. 266-270.

Research output: Contribution to journalArticle

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