Hemisynthesis of methyl pyrethroates from γ-alkoxy-alkylidene malonates and isopropylidenediphenylsulfurane and isopropylidenetriphenylphosphorane

A. Krief; A. Froidbise

doi:10.1016/j.tet.2004.06.035

Hemisynthesis of methyl pyrethroates from γ-alkoxy-alkylidene malonates and isopropylidenediphenylsulfurane and isopropylidenetriphenylphosphorane

A. Krief, A. Froidbise

Unit of organic chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Hemisynthesis of methyl pyrethroates from γ-alkoxy-alkylidene malonates and isopropylidenediphenylsulfurane and isopropylidenetriphenylphosphorane is disclosed. It takes advantage of the high degree of stereocontrol observed in the cyclopropanation of γ-alkoxy- alkylidene malonates by the above mentioned ylides.

Original language	English
Pages (from-to)	7637-7658
Number of pages	22
Journal	Tetrahedron
Volume	60
Issue number	35
DOIs	https://doi.org/10.1016/j.tet.2004.06.035
Publication status	Published - 23 Aug 2004

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10.1016/j.tet.2004.06.035

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title = "Hemisynthesis of methyl pyrethroates from γ-alkoxy-alkylidene malonates and isopropylidenediphenylsulfurane and isopropylidenetriphenylphosphorane",

abstract = "Hemisynthesis of methyl pyrethroates from γ-alkoxy-alkylidene malonates and isopropylidenediphenylsulfurane and isopropylidenetriphenylphosphorane is disclosed. It takes advantage of the high degree of stereocontrol observed in the cyclopropanation of γ-alkoxy- alkylidene malonates by the above mentioned ylides.",

author = "A. Krief and A. Froidbise",

year = "2004",

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doi = "10.1016/j.tet.2004.06.035",

language = "English",

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journal = "Tetrahedron",

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AU - Krief, A.

AU - Froidbise, A.

PY - 2004/8/23

Y1 - 2004/8/23

N2 - Hemisynthesis of methyl pyrethroates from γ-alkoxy-alkylidene malonates and isopropylidenediphenylsulfurane and isopropylidenetriphenylphosphorane is disclosed. It takes advantage of the high degree of stereocontrol observed in the cyclopropanation of γ-alkoxy- alkylidene malonates by the above mentioned ylides.

AB - Hemisynthesis of methyl pyrethroates from γ-alkoxy-alkylidene malonates and isopropylidenediphenylsulfurane and isopropylidenetriphenylphosphorane is disclosed. It takes advantage of the high degree of stereocontrol observed in the cyclopropanation of γ-alkoxy- alkylidene malonates by the above mentioned ylides.

UR - http://www.scopus.com/inward/record.url?scp=3843141862&partnerID=8YFLogxK

U2 - 10.1016/j.tet.2004.06.035

DO - 10.1016/j.tet.2004.06.035

M3 - Article

AN - SCOPUS:3843141862

SN - 0040-4020

VL - 60

SP - 7637

EP - 7658

JO - Tetrahedron

JF - Tetrahedron

IS - 35

ER -

Hemisynthesis of methyl pyrethroates from γ-alkoxy-alkylidene malonates and isopropylidenediphenylsulfurane and isopropylidenetriphenylphosphorane

Abstract

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