Experimental and theoretical determination of the first-order hyperpolarizability of photo- and acidochromic indolino[2,1-b]oxazolidines

F. Castet; L. Ducasse; B. Champagne; L. Sanguinet; J. L. Pozzo; F. Adamietz; V. Rodriguez

doi:10.1016/j.synthmet.2005.09.021

Experimental and theoretical determination of the first-order hyperpolarizability of photo- and acidochromic indolino[2,1-b]oxazolidines

F. Castet, L. Ducasse, B. Champagne, L. Sanguinet, J. L. Pozzo, F. Adamietz, V. Rodriguez

Unit of theoretical and structural physico-chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We report first-order hyperpolarizability studies of a new series of photo- and acidochromic compounds based on the 10-(2-arylethenyl)indolino[2,1-b] oxazolidine unit combined with various styrylic residues, through polarized hyper-Rayleigh scattering measurements and quantum chemical calculations. The reversible photo- and acido-induced oxazolinic ring opening is accompanied by a major change in the conjugation of the π electrons and therefore NLO-phores are generated. Structure-property relationships concerning intrinsic molecular non-linearity of these multiaddressable molecular switches are presented.

Original language	English
Pages (from-to)	393-397
Number of pages	5
Journal	Synthetic Metals
Volume	155
Issue number	2
DOIs	https://doi.org/10.1016/j.synthmet.2005.09.021
Publication status	Published - 15 Nov 2005

Keywords

Hyperpolarizability
Non-linearity
Oxazolinic ring

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10.1016/j.synthmet.2005.09.021

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title = "Experimental and theoretical determination of the first-order hyperpolarizability of photo- and acidochromic indolino[2,1-b]oxazolidines",

abstract = "We report first-order hyperpolarizability studies of a new series of photo- and acidochromic compounds based on the 10-(2-arylethenyl)indolino[2,1-b] oxazolidine unit combined with various styrylic residues, through polarized hyper-Rayleigh scattering measurements and quantum chemical calculations. The reversible photo- and acido-induced oxazolinic ring opening is accompanied by a major change in the conjugation of the π electrons and therefore NLO-phores are generated. Structure-property relationships concerning intrinsic molecular non-linearity of these multiaddressable molecular switches are presented.",

keywords = "Hyperpolarizability, Non-linearity, Oxazolinic ring",

author = "F. Castet and L. Ducasse and B. Champagne and L. Sanguinet and Pozzo, {J. L.} and F. Adamietz and V. Rodriguez",

year = "2005",

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T1 - Experimental and theoretical determination of the first-order hyperpolarizability of photo- and acidochromic indolino[2,1-b]oxazolidines

AU - Castet, F.

AU - Ducasse, L.

AU - Champagne, B.

AU - Sanguinet, L.

AU - Pozzo, J. L.

AU - Adamietz, F.

AU - Rodriguez, V.

PY - 2005/11/15

Y1 - 2005/11/15

N2 - We report first-order hyperpolarizability studies of a new series of photo- and acidochromic compounds based on the 10-(2-arylethenyl)indolino[2,1-b] oxazolidine unit combined with various styrylic residues, through polarized hyper-Rayleigh scattering measurements and quantum chemical calculations. The reversible photo- and acido-induced oxazolinic ring opening is accompanied by a major change in the conjugation of the π electrons and therefore NLO-phores are generated. Structure-property relationships concerning intrinsic molecular non-linearity of these multiaddressable molecular switches are presented.

AB - We report first-order hyperpolarizability studies of a new series of photo- and acidochromic compounds based on the 10-(2-arylethenyl)indolino[2,1-b] oxazolidine unit combined with various styrylic residues, through polarized hyper-Rayleigh scattering measurements and quantum chemical calculations. The reversible photo- and acido-induced oxazolinic ring opening is accompanied by a major change in the conjugation of the π electrons and therefore NLO-phores are generated. Structure-property relationships concerning intrinsic molecular non-linearity of these multiaddressable molecular switches are presented.

KW - Hyperpolarizability

KW - Non-linearity

KW - Oxazolinic ring

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DO - 10.1016/j.synthmet.2005.09.021

M3 - Article

AN - SCOPUS:28544436015

SN - 0379-6779

VL - 155

SP - 393

EP - 397

JO - Synthetic Metals

JF - Synthetic Metals

IS - 2

ER -

Experimental and theoretical determination of the first-order hyperpolarizability of photo- and acidochromic indolino[2,1-b]oxazolidines

Abstract

Keywords

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