Evidence of an equilibrium between selenides and osmium(VIII) reagents and selenoxides and osmium(VI) reagents

A. Krief; A. Destree; V. Durisotti; N. Moreau; C. Smal; C. Colaux-Castillo

Evidence of an equilibrium between selenides and osmium(VIII) reagents and selenoxides and osmium(VI) reagents

A. Krief, A. Destree, V. Durisotti, N. Moreau, C. Smal, C. Colaux-Castillo

Unit of organic chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Driving the equilibrium between selenides and osmium(VIII) reagents with selenoxides and osmium(VI) by a subsequent reaction (rearrangement of allyl selenoxides to allyl alcohols or addition of osmium(VIII) species on C=C double bonds) to one side, allows the transformation of methyl geranyl selenides to linalool and of methyl citronellyl selenoxide to 6,7-dihydroxy citronellyl selenide.

Original language	English
Pages (from-to)	558-559
Number of pages	2
Journal	Chemical Communications
Issue number	6
Publication status	Published - 21 Mar 2002

Cite this

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title = "Evidence of an equilibrium between selenides and osmium(VIII) reagents and selenoxides and osmium(VI) reagents",

abstract = "Driving the equilibrium between selenides and osmium(VIII) reagents with selenoxides and osmium(VI) by a subsequent reaction (rearrangement of allyl selenoxides to allyl alcohols or addition of osmium(VIII) species on C=C double bonds) to one side, allows the transformation of methyl geranyl selenides to linalool and of methyl citronellyl selenoxide to 6,7-dihydroxy citronellyl selenide.",

author = "A. Krief and A. Destree and V. Durisotti and N. Moreau and C. Smal and C. Colaux-Castillo",

year = "2002",

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journal = "Chemical Communications",

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T1 - Evidence of an equilibrium between selenides and osmium(VIII) reagents and selenoxides and osmium(VI) reagents

AU - Krief, A.

AU - Destree, A.

AU - Durisotti, V.

AU - Moreau, N.

AU - Smal, C.

AU - Colaux-Castillo, C.

PY - 2002/3/21

Y1 - 2002/3/21

N2 - Driving the equilibrium between selenides and osmium(VIII) reagents with selenoxides and osmium(VI) by a subsequent reaction (rearrangement of allyl selenoxides to allyl alcohols or addition of osmium(VIII) species on C=C double bonds) to one side, allows the transformation of methyl geranyl selenides to linalool and of methyl citronellyl selenoxide to 6,7-dihydroxy citronellyl selenide.

AB - Driving the equilibrium between selenides and osmium(VIII) reagents with selenoxides and osmium(VI) by a subsequent reaction (rearrangement of allyl selenoxides to allyl alcohols or addition of osmium(VIII) species on C=C double bonds) to one side, allows the transformation of methyl geranyl selenides to linalool and of methyl citronellyl selenoxide to 6,7-dihydroxy citronellyl selenide.

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M3 - Article

AN - SCOPUS:0037149424

SN - 1359-7345

SP - 558

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JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Evidence of an equilibrium between selenides and osmium(VIII) reagents and selenoxides and osmium(VI) reagents

Abstract

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