Enantioselective synthesis of chiral caronic esters: application to the syntheses of (1R)-trans-chrysanthemic acid and its (1R)-cis-dibromo vinyl analogue from dimethyl fumarates

M.J. De Vos; A. Krief

Enantioselective synthesis of chiral caronic esters: application to the syntheses of (1R)-trans-chrysanthemic acid and its (1R)-cis-dibromo vinyl analogue from dimethyl fumarates

M.J. De Vos, A. Krief

Research output: Contribution to journal › Article › peer-review

Abstract

(1R trans chrysanthemic acid and the (1R) cis gem dibromovinyl analogue, constituents respectively of the natural Pyrethrins and of Deltamethrin, the most potent insecticides known, have been stereoselectively prepared from isopropylidene triphenyl phosphorane and di(d)-methyl or di(1)-methyl fumarates respectively.

Original language	English
Pages (from-to)	103-106
Number of pages	4
Journal	Tetrahedron Letters
Volume	24
Issue number	1
Publication status	Published - 1 Jan 1983

Cite this

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Enantioselective synthesis of chiral caronic esters: application to the syntheses of (1R)-trans-chrysanthemic acid and its (1R)-cis-dibromo vinyl analogue from dimethyl fumarates

Abstract

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