Direct Observation of the Reduction of a Molecule on Nitrogen Pairs in Doped Graphene

Mehdi Bouatou, Sourav Mondal, Cyril Chacon, Frédéric Joucken, Yann Girard, Vincent Repain, Amandine Bellec, Sylvie Rousset, Shobhana Narasimhan, Robert Sporken, Yannick J. Dappe, Jérôme Lagoute

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Abstract

Incorporating functional atomic sites in graphene is essential for realizing advanced two-dimensional materials. Doping graphene with nitrogen offers the opportunity to tune its chemical activity with significant charge redistribution occurring between molecules and substrate. The necessary atomic scale understanding of how this depends on the spatial distribution of dopants, as well as their positions relative to the molecule, can be provided by scanning tunneling microscopy. Here we show that a noncovalently bonded molecule such as CoPc undergoes a variable charge transfer when placed on N-doped graphene; on a nitrogen pair, it undergoes a redox reaction with an integral charge transfer whereas a lower fractional charge transfer occurs over a single nitrogen. Thus, the charge state of molecules can be tuned by suitably tailoring the conformation of dopant atoms.

Original languageEnglish
Pages (from-to)6908-6913
Number of pages6
JournalNano Letters
Volume20
Issue number9
DOIs
Publication statusPublished - 9 Sept 2020

Keywords

  • Charge transfer
  • Doped graphene
  • Molecule
  • Scanning tunneling microscopy

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