Direct flow synthesis of H2O2 catalysed by palladium supported on sulfonated polystyrene resins

Research output: Contribution to conferencePoster

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Abstract

Hydrogen peroxide (H2O2) has a wide application range in industry. It is a strong oxidant used e.g. for bleaching, water treatment, semiconductor wafer cleaning and propylene oxide synthesis. It is produced on large scale by the anthraquinone process to yield highly concentrated (50–70 wt%) product in a routine fashion. Nevertheless, this process is very energy consuming, generates a lot of waste and requires transport of hazardous quantities of H2O2. Therefore, direct H2O2 synthesis (starting from gaseous H2 and O2) has recently emerged as a viable alternative.1 Flow chemistry using microreactor technology has made its entry into this field, offering opportunities for safer and efficient process operation.2
Metal catalysts supported on strongly acidic macroreticular polystyrene resins have also been successfully applied for this transformation.3 In this work, we describe a transfer of this type of catalysis into flow technology. The preparation and characterization of a number of catalysts are described, followed by a presentation of their catalytic performances in the direct H2O2 synthesis. We have been able to obtain more than 2 wt% of H2O2 with selectivities exceeding 30-40% in the best cases. These results are superior to most current literature results regarding direct H2O2 synthesis in flow.
Original languageEnglish
PagesP209
Number of pages1
Publication statusPublished - 17 Feb 2015
EventFlow Chemistry Europe 2015 - Berlin, Germany
Duration: 17 Feb 201518 Feb 2015

Conference

ConferenceFlow Chemistry Europe 2015
CountryGermany
CityBerlin
Period17/02/1518/02/15

Keywords

  • flow chemistry, hydrogen peroxide

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  • Projects

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  • Activities

    • 1 Participation to a Symposium, a study Day
    • 1 Participation in conference
    • 1 Participation in workshop, seminar, course

    FLOW CHEMISTRY WORKSHOP 2016

    Eduard Dolusic (Poster)

    18 Jan 201619 Jan 2016

    Activity: Participating in or organising an event typesParticipation in workshop, seminar, course

    19th SIGMA-ALDRICH Organic Synthesis Meeting

    Eduard Dolusic (Poster)

    10 Dec 201511 Dec 2015

    Activity: Participating in or organising an event typesParticipation to a Symposium, a study Day

    Flow Chemistry Europe 2015

    Eduard Dolusic (Poster)

    17 Feb 2015

    Activity: Participating in or organising an event typesParticipation in conference

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