Diastereoselective bromination of compounds bearing a cyclohex-3-enol moiety: Application to the enantioselective synthesis of (1R)-cis-deltamethrinic acid

A. Krief; S. Jeanmart; A. Kremer

doi:10.1021/jo8022507

Diastereoselective bromination of compounds bearing a cyclohex-3-enol moiety: Application to the enantioselective synthesis of (1R)-cis-deltamethrinic acid

A. Krief, S. Jeanmart, A. Kremer

Research output: Contribution to journal › Article › peer-review

Abstract

(Chemical Equation Presented) (1R)-cis-Chrysanthemic acid has been prepared in a few steps with complete control of the relative and absolute stereochemistry. Some mechanistic aspect of the addition of bromine to the C,C double bond of 2,2,5,5-tetramethylcyclohex-3-enol is disclosed. © 2008 American Chemical Society.

Original language	English
Pages (from-to)	9795-9797
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	73
Issue number	24
DOIs	https://doi.org/10.1021/jo8022507
Publication status	Published - 19 Dec 2008

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abstract = "(Chemical Equation Presented) (1R)-cis-Chrysanthemic acid has been prepared in a few steps with complete control of the relative and absolute stereochemistry. Some mechanistic aspect of the addition of bromine to the C,C double bond of 2,2,5,5-tetramethylcyclohex-3-enol is disclosed. {\textcopyright} 2008 American Chemical Society.",

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AU - Jeanmart, S.

AU - Kremer, A.

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N2 - (Chemical Equation Presented) (1R)-cis-Chrysanthemic acid has been prepared in a few steps with complete control of the relative and absolute stereochemistry. Some mechanistic aspect of the addition of bromine to the C,C double bond of 2,2,5,5-tetramethylcyclohex-3-enol is disclosed. © 2008 American Chemical Society.

AB - (Chemical Equation Presented) (1R)-cis-Chrysanthemic acid has been prepared in a few steps with complete control of the relative and absolute stereochemistry. Some mechanistic aspect of the addition of bromine to the C,C double bond of 2,2,5,5-tetramethylcyclohex-3-enol is disclosed. © 2008 American Chemical Society.

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DO - 10.1021/jo8022507

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JF - Journal of Organic Chemistry

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Diastereoselective bromination of compounds bearing a cyclohex-3-enol moiety: Application to the enantioselective synthesis of (1R)-cis-deltamethrinic acid

Abstract

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