Diastereoselective bromination of compounds bearing a cyclohex-3-enol moiety: Application to the enantioselective synthesis of (1R)-cis-deltamethrinic acid

A. Krief, S. Jeanmart, A. Kremer

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Abstract

(Chemical Equation Presented) (1R)-cis-Chrysanthemic acid has been prepared in a few steps with complete control of the relative and absolute stereochemistry. Some mechanistic aspect of the addition of bromine to the C,C double bond of 2,2,5,5-tetramethylcyclohex-3-enol is disclosed. © 2008 American Chemical Society.
Original languageEnglish
Pages (from-to)9795-9797
Number of pages3
JournalJournal of Organic Chemistry
Volume73
Issue number24
DOIs
Publication statusPublished - 19 Dec 2008

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Bearings (structural)
Bromine
Stereochemistry
chrysanthemic acid
deltamethrinic acid

Cite this

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abstract = "(Chemical Equation Presented) (1R)-cis-Chrysanthemic acid has been prepared in a few steps with complete control of the relative and absolute stereochemistry. Some mechanistic aspect of the addition of bromine to the C,C double bond of 2,2,5,5-tetramethylcyclohex-3-enol is disclosed. {\circledC} 2008 American Chemical Society.",
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AU - Jeanmart, S.

AU - Kremer, A.

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AB - (Chemical Equation Presented) (1R)-cis-Chrysanthemic acid has been prepared in a few steps with complete control of the relative and absolute stereochemistry. Some mechanistic aspect of the addition of bromine to the C,C double bond of 2,2,5,5-tetramethylcyclohex-3-enol is disclosed. © 2008 American Chemical Society.

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