Diastereoselective additions to C,C double bonds applied to the enantioselective synthesis of pyrethroic acids

A. Krief; A. Froidbise

doi:10.2174/157019305774322680

Diastereoselective additions to C,C double bonds applied to the enantioselective synthesis of pyrethroic acids

A. Krief, A. Froidbise

Research output: Contribution to journal › Article › peer-review

Abstract

Detailed review on enantioselective synthesis of methyl (IR)-trans-chrysanthemate and related methyl (IR)-cis-deltamethrinate is presented. These commercially available esters of vinylcyclopropanecarboxylic acids belong to pyrethroids class of insecticides. They are used as single enantiomers for domestic and agricultural purpose. They are almost 3.5 10 more active than DDT and are biodegradable.

Original language	English
Pages (from-to)	299-312
Number of pages	14
Journal	Mini-Reviews in Organic Chemistry
Volume	2
Issue number	4
DOIs	https://doi.org/10.2174/157019305774322680
Publication status	Published - 1 Oct 2005

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abstract = "Detailed review on enantioselective synthesis of methyl (IR)-trans-chrysanthemate and related methyl (IR)-cis-deltamethrinate is presented. These commercially available esters of vinylcyclopropanecarboxylic acids belong to pyrethroids class of insecticides. They are used as single enantiomers for domestic and agricultural purpose. They are almost 3.5 10 more active than DDT and are biodegradable.",

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AB - Detailed review on enantioselective synthesis of methyl (IR)-trans-chrysanthemate and related methyl (IR)-cis-deltamethrinate is presented. These commercially available esters of vinylcyclopropanecarboxylic acids belong to pyrethroids class of insecticides. They are used as single enantiomers for domestic and agricultural purpose. They are almost 3.5 10 more active than DDT and are biodegradable.

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Diastereoselective additions to C,C double bonds applied to the enantioselective synthesis of pyrethroic acids

Abstract

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