TY - JOUR
T1 - Deposition of functional organic thin films by pulsed plasma polymerization
T2 - A joint theoretical and experimental study
AU - Denis, Laurent
AU - Marsal, Philippe
AU - Olivier, Yoann
AU - Godfroid, Thomas
AU - Lazzaroni, Roberto
AU - Hecq, Michel
AU - Cornil, Jérôme
AU - Snyders, Rony
PY - 2010/2/22
Y1 - 2010/2/22
N2 - The pulsed plasma polymerization of allylamine and cyclopropylamine is investigated to study the influence of the precursor chemical structure on the process selectivity toward the primary amine groups. Both systems are compared under similar mean powers injected in the discharges (Pmean). The results reveal an increase in the precursor fragmentation in the plasma and a decrease in the primary amine content of the film (%NH2) as P mean increases. Nevertheless, below a critical Pmean value, different behaviors are observed depending on the precursor, cyclopropylamine being less plasma-fragmented than allylamine. As a result, plasma polymer films (PPF) synthesized from cyclopropylamine yield the largest %NH2. These results are rationalized with the help of theoretical calculations pointing to a preferential opening of the cyclopropylamine ring structure. Cyclopropylamine activation in the plasma can thus be achieved without fragmentation reactions, leading to a more efficient incorporation of the -NH2 group of the precursor in the PPF.
AB - The pulsed plasma polymerization of allylamine and cyclopropylamine is investigated to study the influence of the precursor chemical structure on the process selectivity toward the primary amine groups. Both systems are compared under similar mean powers injected in the discharges (Pmean). The results reveal an increase in the precursor fragmentation in the plasma and a decrease in the primary amine content of the film (%NH2) as P mean increases. Nevertheless, below a critical Pmean value, different behaviors are observed depending on the precursor, cyclopropylamine being less plasma-fragmented than allylamine. As a result, plasma polymer films (PPF) synthesized from cyclopropylamine yield the largest %NH2. These results are rationalized with the help of theoretical calculations pointing to a preferential opening of the cyclopropylamine ring structure. Cyclopropylamine activation in the plasma can thus be achieved without fragmentation reactions, leading to a more efficient incorporation of the -NH2 group of the precursor in the PPF.
UR - http://www.scopus.com/inward/record.url?scp=77049091870&partnerID=8YFLogxK
U2 - 10.1002/ppap.200900131
DO - 10.1002/ppap.200900131
M3 - Article
AN - SCOPUS:77049091870
SN - 1612-8850
VL - 7
SP - 172
EP - 181
JO - Plasma Processes and Polymers
JF - Plasma Processes and Polymers
IS - 2
ER -