Comparison between alkylseleno, arylseleno and arylthio substituents stabilizing alkyllithium compounds

A. Krief, W. Dumont, M. Clarembeau, E. Badaoui

Research output: Contribution to journalArticlepeer-review

Abstract

This paper discloses the chemoselective cleavage of selenoacetals. Informations concerning the intimate mechanism of such process are produced as well as unambiguous experimental results concerning the relative stabilization of a carbanionic center by phenylthio, phenylseleno and methylseleno moieties.
Original languageEnglish
Pages (from-to)2023-2030
Number of pages8
JournalTetrahedron
Volume45
Issue number7
Publication statusPublished - 1 Jan 1989

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