Chemical bonding between laser welded aluminum and nylon-6.6

Pierre Hirchenhahn, Adham Al Sayyad, Julien Bardon, Alexandre Felten, Peter Plapper, Laurent Houssiau

Research output: Contribution to conferenceOther

Abstract

As concerns for climate change are growing, the automotive industry seeks lightweight structures and therefore has a raising interest in polymer/metal assemblies. Such assemblies also find applications in the biomedical field e.g. for implants. There are three ways to assemble such dissimilar materials: by mechanical fastening, adhesive bonding and welding. The mechanical option does not comply to the weight reduction objective, as well as it badly resists to corrosion. Adhesive bonding is doing better in weight reduction, but do not provide an optimum solution for biomedical applications, since adhesives are generally not biocompatible. Welding techniques, especially laser welding, are promising techniques. Indeed laser welding is fast, adaptable to complex geometries and solvent free, which are major assets for industrial applications [1]. Despite the great application potential, the root causes of the adhesion are not well understood. The adhesion theory proposes four mechanisms: mechanical interlocking, diffusion, chemical bonding, and electrostatic interactions. This work focuses on understanding chemical bonding at the interface of aluminum and polyamide-6.6, which are materials commonly used in automotive industry. Using a combination of ToF-SIMS and XPS, three types of samples were analyzed. First the interface of “industrial” like samples were analyzed. To access the interface, the assemblies were broken and polyamide residues on aluminum were dissolved. The results show that a very thin polymer layer remains in the joint area, since typical polyamide-6.6 ions NH-, CN-, CNO-, NH4+, CH4N+, CH2NO+ are detected. Some hybrid ions could also be identified, like CHNAl-, CHNOAl+/-, CH3NO2Al+/-, giving hints of a C-O-Al or a C-N-Al type of bonding. Secondly, the interface of “model” samples were analyzed. The aluminum surface was first mirror polished, then spin-coated with polyamide, welded from the opposite side of the aluminum plate and finally the polymer film was dissolved to access the interface. Here again polymer could be identified in the joint area, and the nature of the bond seems to be of C-O-Al nature, but C-N-Al bonds cannot be excluded. In a third step, N-methylformamide, a molecule similar to the reactive part of the nylon-6.6 molecule, was dip-coated on aluminum surfaces and directly analyzed. Results show that CHNAl+/- ions are originating from recombination effects, so that the only bond possible between both materials is of C-O-Al nature. Finally, a reaction mechanism involving aluminum hydroxide and the amide group of the polymer is proposed.

[1] Amancio-Filho ST, Dos Santos JF. Joining of Polymers and Polymer-Metal Hybrid Structures: Recent Developments and Trends. Polym Eng Sci 2009;47:21–5. doi:10.1002/pen.
Original languageEnglish
Publication statusUnpublished - 2019
EventSIMS XXII - Kyoto, Japan
Duration: 20 Oct 201925 Oct 2019

Conference

ConferenceSIMS XXII
CountryJapan
CityKyoto
Period20/10/1925/10/19

Fingerprint

Nylons
Aluminum
Polymers
Lasers
Adhesives
Laser beam welding
methylformamide
Ions
Automotive industry
Welding
Adhesion
Metals
Aluminum Hydroxide
Dissimilar materials
Molecules
Secondary ion mass spectrometry
Coulomb interactions
Polymer films
Amides
Climate change

Cite this

Hirchenhahn, P., Al Sayyad, A., Bardon, J., Felten, A., Plapper, P., & Houssiau, L. (2019). Chemical bonding between laser welded aluminum and nylon-6.6. SIMS XXII, Kyoto, Japan.
Hirchenhahn, Pierre ; Al Sayyad, Adham ; Bardon, Julien ; Felten, Alexandre ; Plapper, Peter ; Houssiau, Laurent. / Chemical bonding between laser welded aluminum and nylon-6.6. SIMS XXII, Kyoto, Japan.
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title = "Chemical bonding between laser welded aluminum and nylon-6.6",
abstract = "As concerns for climate change are growing, the automotive industry seeks lightweight structures and therefore has a raising interest in polymer/metal assemblies. Such assemblies also find applications in the biomedical field e.g. for implants. There are three ways to assemble such dissimilar materials: by mechanical fastening, adhesive bonding and welding. The mechanical option does not comply to the weight reduction objective, as well as it badly resists to corrosion. Adhesive bonding is doing better in weight reduction, but do not provide an optimum solution for biomedical applications, since adhesives are generally not biocompatible. Welding techniques, especially laser welding, are promising techniques. Indeed laser welding is fast, adaptable to complex geometries and solvent free, which are major assets for industrial applications [1]. Despite the great application potential, the root causes of the adhesion are not well understood. The adhesion theory proposes four mechanisms: mechanical interlocking, diffusion, chemical bonding, and electrostatic interactions. This work focuses on understanding chemical bonding at the interface of aluminum and polyamide-6.6, which are materials commonly used in automotive industry. Using a combination of ToF-SIMS and XPS, three types of samples were analyzed. First the interface of “industrial” like samples were analyzed. To access the interface, the assemblies were broken and polyamide residues on aluminum were dissolved. The results show that a very thin polymer layer remains in the joint area, since typical polyamide-6.6 ions NH-, CN-, CNO-, NH4+, CH4N+, CH2NO+ are detected. Some hybrid ions could also be identified, like CHNAl-, CHNOAl+/-, CH3NO2Al+/-, giving hints of a C-O-Al or a C-N-Al type of bonding. Secondly, the interface of “model” samples were analyzed. The aluminum surface was first mirror polished, then spin-coated with polyamide, welded from the opposite side of the aluminum plate and finally the polymer film was dissolved to access the interface. Here again polymer could be identified in the joint area, and the nature of the bond seems to be of C-O-Al nature, but C-N-Al bonds cannot be excluded. In a third step, N-methylformamide, a molecule similar to the reactive part of the nylon-6.6 molecule, was dip-coated on aluminum surfaces and directly analyzed. Results show that CHNAl+/- ions are originating from recombination effects, so that the only bond possible between both materials is of C-O-Al nature. Finally, a reaction mechanism involving aluminum hydroxide and the amide group of the polymer is proposed.[1] Amancio-Filho ST, Dos Santos JF. Joining of Polymers and Polymer-Metal Hybrid Structures: Recent Developments and Trends. Polym Eng Sci 2009;47:21–5. doi:10.1002/pen.",
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Hirchenhahn, P, Al Sayyad, A, Bardon, J, Felten, A, Plapper, P & Houssiau, L 2019, 'Chemical bonding between laser welded aluminum and nylon-6.6', SIMS XXII, Kyoto, Japan, 20/10/19 - 25/10/19.

Chemical bonding between laser welded aluminum and nylon-6.6. / Hirchenhahn, Pierre; Al Sayyad, Adham; Bardon, Julien; Felten, Alexandre; Plapper, Peter; Houssiau, Laurent.

2019. SIMS XXII, Kyoto, Japan.

Research output: Contribution to conferenceOther

TY - CONF

T1 - Chemical bonding between laser welded aluminum and nylon-6.6

AU - Hirchenhahn, Pierre

AU - Al Sayyad, Adham

AU - Bardon, Julien

AU - Felten, Alexandre

AU - Plapper, Peter

AU - Houssiau, Laurent

PY - 2019

Y1 - 2019

N2 - As concerns for climate change are growing, the automotive industry seeks lightweight structures and therefore has a raising interest in polymer/metal assemblies. Such assemblies also find applications in the biomedical field e.g. for implants. There are three ways to assemble such dissimilar materials: by mechanical fastening, adhesive bonding and welding. The mechanical option does not comply to the weight reduction objective, as well as it badly resists to corrosion. Adhesive bonding is doing better in weight reduction, but do not provide an optimum solution for biomedical applications, since adhesives are generally not biocompatible. Welding techniques, especially laser welding, are promising techniques. Indeed laser welding is fast, adaptable to complex geometries and solvent free, which are major assets for industrial applications [1]. Despite the great application potential, the root causes of the adhesion are not well understood. The adhesion theory proposes four mechanisms: mechanical interlocking, diffusion, chemical bonding, and electrostatic interactions. This work focuses on understanding chemical bonding at the interface of aluminum and polyamide-6.6, which are materials commonly used in automotive industry. Using a combination of ToF-SIMS and XPS, three types of samples were analyzed. First the interface of “industrial” like samples were analyzed. To access the interface, the assemblies were broken and polyamide residues on aluminum were dissolved. The results show that a very thin polymer layer remains in the joint area, since typical polyamide-6.6 ions NH-, CN-, CNO-, NH4+, CH4N+, CH2NO+ are detected. Some hybrid ions could also be identified, like CHNAl-, CHNOAl+/-, CH3NO2Al+/-, giving hints of a C-O-Al or a C-N-Al type of bonding. Secondly, the interface of “model” samples were analyzed. The aluminum surface was first mirror polished, then spin-coated with polyamide, welded from the opposite side of the aluminum plate and finally the polymer film was dissolved to access the interface. Here again polymer could be identified in the joint area, and the nature of the bond seems to be of C-O-Al nature, but C-N-Al bonds cannot be excluded. In a third step, N-methylformamide, a molecule similar to the reactive part of the nylon-6.6 molecule, was dip-coated on aluminum surfaces and directly analyzed. Results show that CHNAl+/- ions are originating from recombination effects, so that the only bond possible between both materials is of C-O-Al nature. Finally, a reaction mechanism involving aluminum hydroxide and the amide group of the polymer is proposed.[1] Amancio-Filho ST, Dos Santos JF. Joining of Polymers and Polymer-Metal Hybrid Structures: Recent Developments and Trends. Polym Eng Sci 2009;47:21–5. doi:10.1002/pen.

AB - As concerns for climate change are growing, the automotive industry seeks lightweight structures and therefore has a raising interest in polymer/metal assemblies. Such assemblies also find applications in the biomedical field e.g. for implants. There are three ways to assemble such dissimilar materials: by mechanical fastening, adhesive bonding and welding. The mechanical option does not comply to the weight reduction objective, as well as it badly resists to corrosion. Adhesive bonding is doing better in weight reduction, but do not provide an optimum solution for biomedical applications, since adhesives are generally not biocompatible. Welding techniques, especially laser welding, are promising techniques. Indeed laser welding is fast, adaptable to complex geometries and solvent free, which are major assets for industrial applications [1]. Despite the great application potential, the root causes of the adhesion are not well understood. The adhesion theory proposes four mechanisms: mechanical interlocking, diffusion, chemical bonding, and electrostatic interactions. This work focuses on understanding chemical bonding at the interface of aluminum and polyamide-6.6, which are materials commonly used in automotive industry. Using a combination of ToF-SIMS and XPS, three types of samples were analyzed. First the interface of “industrial” like samples were analyzed. To access the interface, the assemblies were broken and polyamide residues on aluminum were dissolved. The results show that a very thin polymer layer remains in the joint area, since typical polyamide-6.6 ions NH-, CN-, CNO-, NH4+, CH4N+, CH2NO+ are detected. Some hybrid ions could also be identified, like CHNAl-, CHNOAl+/-, CH3NO2Al+/-, giving hints of a C-O-Al or a C-N-Al type of bonding. Secondly, the interface of “model” samples were analyzed. The aluminum surface was first mirror polished, then spin-coated with polyamide, welded from the opposite side of the aluminum plate and finally the polymer film was dissolved to access the interface. Here again polymer could be identified in the joint area, and the nature of the bond seems to be of C-O-Al nature, but C-N-Al bonds cannot be excluded. In a third step, N-methylformamide, a molecule similar to the reactive part of the nylon-6.6 molecule, was dip-coated on aluminum surfaces and directly analyzed. Results show that CHNAl+/- ions are originating from recombination effects, so that the only bond possible between both materials is of C-O-Al nature. Finally, a reaction mechanism involving aluminum hydroxide and the amide group of the polymer is proposed.[1] Amancio-Filho ST, Dos Santos JF. Joining of Polymers and Polymer-Metal Hybrid Structures: Recent Developments and Trends. Polym Eng Sci 2009;47:21–5. doi:10.1002/pen.

M3 - Other

ER -

Hirchenhahn P, Al Sayyad A, Bardon J, Felten A, Plapper P, Houssiau L. Chemical bonding between laser welded aluminum and nylon-6.6. 2019. SIMS XXII, Kyoto, Japan.