Beryllium dichloride: Efficient promoter for the addition of organolithiums and organomagnesiums to cyclohexen-2-one

A. Krief, M.J. De Vos, S. De Lombart, J. Bosret, F. Couty

Research output: Contribution to journalArticlepeer-review

Abstract

Organoberyllium compounds, generated by transmetallation from Grignard and organolithium reagents react with 2-cyclohexenone to give predominantly the adducts resulting from conjugated addition. The chemoselectivity of this reaction was found to be highly dependent upon the nature of organic moiety and of the conditions used.
Original languageEnglish
Pages (from-to)6295-6298
Number of pages4
JournalTetrahedron Letters
Volume38
Issue number35
DOIs
Publication statusPublished - 1 Sep 1997

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