Beryllium dichloride: Efficient promoter for the addition of organolithiums and organomagnesiums to cyclohexen-2-one

A. Krief; M.J. De Vos; S. De Lombart; J. Bosret; F. Couty

doi:10.1016/S0040-4039(97)01416-0

Beryllium dichloride: Efficient promoter for the addition of organolithiums and organomagnesiums to cyclohexen-2-one

A. Krief, M.J. De Vos, S. De Lombart, J. Bosret, F. Couty

Unit of organic chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Organoberyllium compounds, generated by transmetallation from Grignard and organolithium reagents react with 2-cyclohexenone to give predominantly the adducts resulting from conjugated addition. The chemoselectivity of this reaction was found to be highly dependent upon the nature of organic moiety and of the conditions used.

Original language	English
Pages (from-to)	6295-6298
Number of pages	4
Journal	Tetrahedron Letters
Volume	38
Issue number	35
DOIs	https://doi.org/10.1016/S0040-4039(97)01416-0
Publication status	Published - 1 Sept 1997

Access to Document

10.1016/S0040-4039(97)01416-0

Cite this

@article{7e480930237441ec8d307cc4e046c95e,

title = "Beryllium dichloride: Efficient promoter for the addition of organolithiums and organomagnesiums to cyclohexen-2-one",

abstract = "Organoberyllium compounds, generated by transmetallation from Grignard and organolithium reagents react with 2-cyclohexenone to give predominantly the adducts resulting from conjugated addition. The chemoselectivity of this reaction was found to be highly dependent upon the nature of organic moiety and of the conditions used.",

author = "A. Krief and {De Vos}, M.J. and {De Lombart}, S. and J. Bosret and F. Couty",

year = "1997",

month = sep,

day = "1",

doi = "10.1016/S0040-4039(97)01416-0",

language = "English",

volume = "38",

pages = "6295--6298",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "35",

}

TY - JOUR

T1 - Beryllium dichloride: Efficient promoter for the addition of organolithiums and organomagnesiums to cyclohexen-2-one

AU - Krief, A.

AU - De Vos, M.J.

AU - De Lombart, S.

AU - Bosret, J.

AU - Couty, F.

PY - 1997/9/1

Y1 - 1997/9/1

N2 - Organoberyllium compounds, generated by transmetallation from Grignard and organolithium reagents react with 2-cyclohexenone to give predominantly the adducts resulting from conjugated addition. The chemoselectivity of this reaction was found to be highly dependent upon the nature of organic moiety and of the conditions used.

AB - Organoberyllium compounds, generated by transmetallation from Grignard and organolithium reagents react with 2-cyclohexenone to give predominantly the adducts resulting from conjugated addition. The chemoselectivity of this reaction was found to be highly dependent upon the nature of organic moiety and of the conditions used.

UR - http://www.scopus.com/inward/record.url?scp=0343145647&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(97)01416-0

DO - 10.1016/S0040-4039(97)01416-0

M3 - Article

AN - SCOPUS:0343145647

SN - 0040-4039

VL - 38

SP - 6295

EP - 6298

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 35

ER -

Beryllium dichloride: Efficient promoter for the addition of organolithiums and organomagnesiums to cyclohexen-2-one

Abstract

Access to Document

Other files and links

Fingerprint

Cite this