An expeditious enantioselective synthesis of methyl trans-chrysanthemate

Research output: Contribution to journalArticle

82 Downloads (Pure)

Abstract

Methyl trans-chrysanthemate has been prepared in few steps from isopropylidenediphenylsulfurane and methyl (E)-3-(3,3-dimethyloxiran-2-yl)prop-2-enoate. The latter was obtained from methyl 4-oxobutenoate or 3-methylbut-2-en-1-ol. The Sharpless catalytic epoxidation reaction allows an asymmetric version of this transformation.
Original languageEnglish
Pages (from-to)2019-2022
Number of pages4
JournalSynthesis
Issue number14
Publication statusPublished - 2002

Fingerprint

Epoxidation
prenol

Cite this

@article{6e0e7f0476e84598b3481117147cf6cc,
title = "An expeditious enantioselective synthesis of methyl trans-chrysanthemate",
abstract = "Methyl trans-chrysanthemate has been prepared in few steps from isopropylidenediphenylsulfurane and methyl (E)-3-(3,3-dimethyloxiran-2-yl)prop-2-enoate. The latter was obtained from methyl 4-oxobutenoate or 3-methylbut-2-en-1-ol. The Sharpless catalytic epoxidation reaction allows an asymmetric version of this transformation.",
author = "A. Krief and W. Dumont and D. Baillieul",
year = "2002",
language = "English",
pages = "2019--2022",
journal = "Synthesis",
issn = "0039-7881",
publisher = "Georg Thieme Verlag",
number = "14",

}

An expeditious enantioselective synthesis of methyl trans-chrysanthemate. / Krief, A.; Dumont, W.; Baillieul, D.

In: Synthesis, No. 14, 2002, p. 2019-2022.

Research output: Contribution to journalArticle

TY - JOUR

T1 - An expeditious enantioselective synthesis of methyl trans-chrysanthemate

AU - Krief, A.

AU - Dumont, W.

AU - Baillieul, D.

PY - 2002

Y1 - 2002

N2 - Methyl trans-chrysanthemate has been prepared in few steps from isopropylidenediphenylsulfurane and methyl (E)-3-(3,3-dimethyloxiran-2-yl)prop-2-enoate. The latter was obtained from methyl 4-oxobutenoate or 3-methylbut-2-en-1-ol. The Sharpless catalytic epoxidation reaction allows an asymmetric version of this transformation.

AB - Methyl trans-chrysanthemate has been prepared in few steps from isopropylidenediphenylsulfurane and methyl (E)-3-(3,3-dimethyloxiran-2-yl)prop-2-enoate. The latter was obtained from methyl 4-oxobutenoate or 3-methylbut-2-en-1-ol. The Sharpless catalytic epoxidation reaction allows an asymmetric version of this transformation.

UR - http://www.scopus.com/inward/record.url?scp=0036398492&partnerID=8YFLogxK

M3 - Article

SP - 2019

EP - 2022

JO - Synthesis

JF - Synthesis

SN - 0039-7881

IS - 14

ER -