Adaptability of the metal(III,IV) 1,2,3-trioxobenzene rod secondary building unit for the production of chemically stable and catalytically actIVe MOFs

Georges Mouchaham, Brian Abeykoon, Mónica Giménez-Marqués, Sergio Navalon, Andrea Santiago-Portillo, Maame Affram, Nathalie Guillou, Charlotte Martineau, Hermenegildo Garcia, Alexandra Fateeva, Thomas Devic

Research output: Contribution to journalArticlepeer-review

Abstract

The use of a 5,10,15,20-tetrakis(3,4,5-trihydroxyphenyl)porphyrin has yielded a new MOF based on M-1,2,3-trioxobenzene chains that can be made of M = Zr(iv) or RE(iii) (RE = rare earth), showing a very high and limited chemical stability, respectively. The robust metallated Zr-analogue, Co-MIL-173(Zr), has proven to be a heme-like heterogeneous catalyst suitable for aerobic oxidation of hydrocarbons.

Original languageEnglish
Pages (from-to)7661-7664
Number of pages4
JournalChemical Communications
Volume53
Issue number54
DOIs
Publication statusPublished - 2017
Externally publishedYes

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