A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

Hamed Mahmoudi, Federica Valentini, Francesco Ferlin, Lucia Anna Bivona, Ioannis Anastasiou, Luca Fusaro, Carmela Aprile, Assunta Marrocchi, Luigi Vaccaro

Research output: Contribution to journalArticle

Abstract

The [PdCl 4] 2- palladium complex has been immobilized on a polystyrene-type resin loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd(ii)-POLI-TAG) has proved to be highly active in the definition of an efficient protocol for the Heck-Mizoroki coupling reaction under batch and flow conditions. Importantly, it is shown to be highly robust in combination with a safe non-toxic reaction medium, i.e. biomass-derived GVL, since it could be reused for multiple runs without significantly losing its activity.

Original languageEnglish
Pages (from-to)355-360
Number of pages6
JournalGreen Chemistry
Volume21
Issue number2
DOIs
Publication statusPublished - 2019

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Polystyrenes
palladium
Palladium
Binding sites
Leaching
resin
Biomass
Resins
catalyst
Binding Sites
leaching
Catalysts
biomass
protocol

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Mahmoudi, Hamed ; Valentini, Federica ; Ferlin, Francesco ; Bivona, Lucia Anna ; Anastasiou, Ioannis ; Fusaro, Luca ; Aprile, Carmela ; Marrocchi, Assunta ; Vaccaro, Luigi. / A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL. In: Green Chemistry. 2019 ; Vol. 21, No. 2. pp. 355-360.
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A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL. / Mahmoudi, Hamed; Valentini, Federica; Ferlin, Francesco; Bivona, Lucia Anna; Anastasiou, Ioannis; Fusaro, Luca; Aprile, Carmela; Marrocchi, Assunta; Vaccaro, Luigi.

In: Green Chemistry, Vol. 21, No. 2, 2019, p. 355-360.

Research output: Contribution to journalArticle

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AU - Mahmoudi, Hamed

AU - Valentini, Federica

AU - Ferlin, Francesco

AU - Bivona, Lucia Anna

AU - Anastasiou, Ioannis

AU - Fusaro, Luca

AU - Aprile, Carmela

AU - Marrocchi, Assunta

AU - Vaccaro, Luigi

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