A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

Hamed Mahmoudi; Federica Valentini; Francesco Ferlin; Lucia Anna Bivona; Ioannis Anastasiou; Luca Fusaro; Carmela Aprile; Assunta Marrocchi; Luigi Vaccaro

doi:10.1039/c8gc03228a

A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

Hamed Mahmoudi, Federica Valentini, Francesco Ferlin, Lucia Anna Bivona, Ioannis Anastasiou, Luca Fusaro, Carmela Aprile, Assunta Marrocchi, Luigi Vaccaro

Research output: Contribution to journal › Article › peer-review

Abstract

The [PdCl ₄] ^2- palladium complex has been immobilized on a polystyrene-type resin loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd(ii)-POLI-TAG) has proved to be highly active in the definition of an efficient protocol for the Heck-Mizoroki coupling reaction under batch and flow conditions. Importantly, it is shown to be highly robust in combination with a safe non-toxic reaction medium, i.e. biomass-derived GVL, since it could be reused for multiple runs without significantly losing its activity.

Original language	English
Pages (from-to)	355-360
Number of pages	6
Journal	Green Chemistry
Volume	21
Issue number	2
DOIs	https://doi.org/10.1039/c8gc03228a
Publication status	Published - 2019

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1039/c8gc03228a

Cite this

@article{f825c6aa65e74c92bc4c91fd9f367ea8,

title = "A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL",

abstract = "The [PdCl 4] 2- palladium complex has been immobilized on a polystyrene-type resin loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd(ii)-POLI-TAG) has proved to be highly active in the definition of an efficient protocol for the Heck-Mizoroki coupling reaction under batch and flow conditions. Importantly, it is shown to be highly robust in combination with a safe non-toxic reaction medium, i.e. biomass-derived GVL, since it could be reused for multiple runs without significantly losing its activity. ",

author = "Hamed Mahmoudi and Federica Valentini and Francesco Ferlin and Bivona, {Lucia Anna} and Ioannis Anastasiou and Luca Fusaro and Carmela Aprile and Assunta Marrocchi and Luigi Vaccaro",

note = "Funding Information: F. V., F. F., I. A., A. M., and L. V. gratefully acknowledge the Universit{\`a} degli Studi di Perugia and MIUR for financial support to the project AMIS, through the program “Dipartimenti di Eccellenza – 2018-2022”. The authors acknowledge Dr Pierre Louette for his support in the XPS analysis. This research used the resources of the “Plateforme Technologique Physico-Chemical Characterization” – PC2 located at the University of Namur. Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2019",

doi = "10.1039/c8gc03228a",

language = "English",

volume = "21",

pages = "355--360",

journal = "Green Chemistry",

issn = "1463-9270",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

AU - Mahmoudi, Hamed

AU - Valentini, Federica

AU - Ferlin, Francesco

AU - Bivona, Lucia Anna

AU - Anastasiou, Ioannis

AU - Fusaro, Luca

AU - Aprile, Carmela

AU - Marrocchi, Assunta

AU - Vaccaro, Luigi

N1 - Funding Information: F. V., F. F., I. A., A. M., and L. V. gratefully acknowledge the Università degli Studi di Perugia and MIUR for financial support to the project AMIS, through the program “Dipartimenti di Eccellenza – 2018-2022”. The authors acknowledge Dr Pierre Louette for his support in the XPS analysis. This research used the resources of the “Plateforme Technologique Physico-Chemical Characterization” – PC2 located at the University of Namur. Publisher Copyright: © 2019 The Royal Society of Chemistry. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2019

Y1 - 2019

N2 - The [PdCl 4] 2- palladium complex has been immobilized on a polystyrene-type resin loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd(ii)-POLI-TAG) has proved to be highly active in the definition of an efficient protocol for the Heck-Mizoroki coupling reaction under batch and flow conditions. Importantly, it is shown to be highly robust in combination with a safe non-toxic reaction medium, i.e. biomass-derived GVL, since it could be reused for multiple runs without significantly losing its activity.

AB - The [PdCl 4] 2- palladium complex has been immobilized on a polystyrene-type resin loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd(ii)-POLI-TAG) has proved to be highly active in the definition of an efficient protocol for the Heck-Mizoroki coupling reaction under batch and flow conditions. Importantly, it is shown to be highly robust in combination with a safe non-toxic reaction medium, i.e. biomass-derived GVL, since it could be reused for multiple runs without significantly losing its activity.

UR - http://www.scopus.com/inward/record.url?scp=85060391624&partnerID=8YFLogxK

U2 - 10.1039/c8gc03228a

DO - 10.1039/c8gc03228a

M3 - Article

SN - 1463-9270

VL - 21

SP - 355

EP - 360

JO - Green Chemistry

JF - Green Chemistry

IS - 2

ER -

A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

Abstract

UN SDGs

Access to Document

Other files and links

Embargoed Document

Fingerprint

Physical Chemistry and characterization(PC2)

Cite this

A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

Abstract

UN SDGs

Access to Document

Other files and links

Embargoed Document

Fingerprint

Equipment

Physical Chemistry and characterization(PC2)

Cite this