A Simple and Efficient Mechanochemical Route for the Synthesis of Salophen Ligands and of the Corresponding Zn, Ni, and Pd Complexes

Luca Fusaro, Andrea Carletta, Jean Dubois, Nikolay Tumanov, Carmela Aprile, Johan Wouters, Antonella Dalla Cort, Luca Leoni

Research output: Contribution to journal › Article

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Abstract

A number of salophen ligands and their Zn, Ni, and Pd complexes were synthesized by anefficient one-pot mechanosynthesis protocol. The reaction products were characterized by means ofcomplementary solid-state techniques, i.e., powder X-ray diffraction, single-crystal X-ray diffraction,and solid-state NMR spectroscopy. Four new crystal structures of metal salophen complexes as DMSOsolvates are here reported. The described simple and relatively fast (about 1 h for all derivatives)procedure is a good alternative to classical methods performed in organic solvents.
Original languageEnglish
Article number2314
Pages (from-to)2314
Number of pages11
JournalMolecules
Volume24
Issue number12
DOIs
Publication statusPublished - 1 Jan 2019

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X-Ray Diffraction
routes
Ligands
solid state
ligands
Coordination Complexes
synthesis
Metal complexes
Reaction products
diffraction
reaction products
Powders
X ray powder diffraction
Organic solvents
Nuclear magnetic resonance spectroscopy
x rays
Magnetic Resonance Spectroscopy
Crystal structure
Single crystals
Derivatives

Keywords

  • salophen ligands
  • metal salophen complexes
  • mechanochemistry
  • Metal salophen complexes
  • Salophen ligands
  • Mechanochemistry

Cite this

Fusaro, Luca ; Carletta, Andrea ; Dubois, Jean ; Tumanov, Nikolay ; Aprile, Carmela ; Wouters, Johan ; Dalla Cort, Antonella ; Leoni, Luca. / A Simple and Efficient Mechanochemical Route for the Synthesis of Salophen Ligands and of the Corresponding Zn, Ni, and Pd Complexes. In: Molecules. 2019 ; Vol. 24, No. 12. pp. 2314.
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abstract = "A number of salophen ligands and their Zn, Ni, and Pd complexes were synthesized by anefficient one-pot mechanosynthesis protocol. The reaction products were characterized by means ofcomplementary solid-state techniques, i.e., powder X-ray diffraction, single-crystal X-ray diffraction,and solid-state NMR spectroscopy. Four new crystal structures of metal salophen complexes as DMSOsolvates are here reported. The described simple and relatively fast (about 1 h for all derivatives)procedure is a good alternative to classical methods performed in organic solvents.",
keywords = "salophen ligands, metal salophen complexes, mechanochemistry, Metal salophen complexes, Salophen ligands, Mechanochemistry",
author = "Luca Fusaro and Andrea Carletta and Jean Dubois and Nikolay Tumanov and Carmela Aprile and Johan Wouters and {Dalla Cort}, Antonella and Luca Leoni",
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Fusaro, L, Carletta, A, Dubois, J, Tumanov, N, Aprile, C, Wouters, J, Dalla Cort, A & Leoni, L 2019, 'A Simple and Efficient Mechanochemical Route for the Synthesis of Salophen Ligands and of the Corresponding Zn, Ni, and Pd Complexes', Molecules, vol. 24, no. 12, 2314, pp. 2314. https://doi.org/10.3390/molecules24122314

A Simple and Efficient Mechanochemical Route for the Synthesis of Salophen Ligands and of the Corresponding Zn, Ni, and Pd Complexes. / Fusaro, Luca; Carletta, Andrea; Dubois, Jean; Tumanov, Nikolay; Aprile, Carmela; Wouters, Johan; Dalla Cort, Antonella; Leoni, Luca.

In: Molecules, Vol. 24, No. 12, 2314, 01.01.2019, p. 2314.

Research output: Contribution to journal › Article

TY - JOUR

T1 - A Simple and Efficient Mechanochemical Route for the Synthesis of Salophen Ligands and of the Corresponding Zn, Ni, and Pd Complexes

AU - Fusaro, Luca

AU - Carletta, Andrea

AU - Dubois, Jean

AU - Tumanov, Nikolay

AU - Aprile, Carmela

AU - Wouters, Johan

AU - Dalla Cort, Antonella

AU - Leoni, Luca

PY - 2019/1/1

Y1 - 2019/1/1

N2 - A number of salophen ligands and their Zn, Ni, and Pd complexes were synthesized by anefficient one-pot mechanosynthesis protocol. The reaction products were characterized by means ofcomplementary solid-state techniques, i.e., powder X-ray diffraction, single-crystal X-ray diffraction,and solid-state NMR spectroscopy. Four new crystal structures of metal salophen complexes as DMSOsolvates are here reported. The described simple and relatively fast (about 1 h for all derivatives)procedure is a good alternative to classical methods performed in organic solvents.

AB - A number of salophen ligands and their Zn, Ni, and Pd complexes were synthesized by anefficient one-pot mechanosynthesis protocol. The reaction products were characterized by means ofcomplementary solid-state techniques, i.e., powder X-ray diffraction, single-crystal X-ray diffraction,and solid-state NMR spectroscopy. Four new crystal structures of metal salophen complexes as DMSOsolvates are here reported. The described simple and relatively fast (about 1 h for all derivatives)procedure is a good alternative to classical methods performed in organic solvents.

KW - salophen ligands

KW - metal salophen complexes

KW - mechanochemistry

KW - Metal salophen complexes

KW - Salophen ligands

KW - Mechanochemistry

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U2 - 10.3390/molecules24122314

DO - 10.3390/molecules24122314

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JF - Molecules

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Fusaro L, Carletta A, Dubois J, Tumanov N, Aprile C, Wouters J et al. A Simple and Efficient Mechanochemical Route for the Synthesis of Salophen Ligands and of the Corresponding Zn, Ni, and Pd Complexes. Molecules. 2019 Jan 1;24(12):2314. 2314. https://doi.org/10.3390/molecules24122314

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