A New Analysis of Rovibrational Bands of Propyne in the 10-, 16-, and 30-μm Regions

G. Graner, R. Farrenq, G. Blanquet, J. Walrand, K. Pekkala

Research output: Contribution to journalArticle

Abstract

After the most prominent bands of propyne (CHCCH) in the region of 9-11, 16, and 30 μm have been analyzed, we have undertaken the study of weaker bands in the same regions. The main purpose of this study is to reach all levels in the 900-1100 cm energy range, in order to make possible a global treatment of all these interacting levels. High-resolution Fourier transform spectra have been used in all three regions and also tunable diode laser spectra in the 16-μm region. The major findings concern the (ν + ν) PAPE band at 10μm, the (ν + ν) - ν and (ν + ν) - ν hot bands at 16 μm, and the (3ν) - (2ν) and (3ν) - (2ν) "superhot hands" at 30 μm. Several local resonances in these bands have also been detected.
Original languageEnglish
Pages (from-to)80-101
Number of pages22
JournalJournal of molecular spectroscopy
Volume161
Issue number1
DOIs
Publication statusPublished - 1 Sep 1993

Fingerprint

Semiconductor lasers
Fourier transforms
semiconductor lasers
methylacetylene
high resolution
energy

Cite this

@article{0bf0742188ea4f58a449af63fbf7f4b0,
title = "A New Analysis of Rovibrational Bands of Propyne in the 10-, 16-, and 30-μm Regions",
abstract = "After the most prominent bands of propyne (CHCCH) in the region of 9-11, 16, and 30 μm have been analyzed, we have undertaken the study of weaker bands in the same regions. The main purpose of this study is to reach all levels in the 900-1100 cm energy range, in order to make possible a global treatment of all these interacting levels. High-resolution Fourier transform spectra have been used in all three regions and also tunable diode laser spectra in the 16-μm region. The major findings concern the (ν + ν) PAPE band at 10μm, the (ν + ν) - ν and (ν + ν) - ν hot bands at 16 μm, and the (3ν) - (2ν) and (3ν) - (2ν) {"}superhot hands{"} at 30 μm. Several local resonances in these bands have also been detected.",
author = "G. Graner and R. Farrenq and G. Blanquet and J. Walrand and K. Pekkala",
note = "Copyright 2008 Elsevier B.V., All rights reserved.",
year = "1993",
month = "9",
day = "1",
doi = "10.1006/jmsp.1993.1217",
language = "English",
volume = "161",
pages = "80--101",
journal = "Journal of molecular spectroscopy",
issn = "0022-2852",
publisher = "Academic Press Inc.",
number = "1",

}

A New Analysis of Rovibrational Bands of Propyne in the 10-, 16-, and 30-μm Regions. / Graner, G.; Farrenq, R.; Blanquet, G.; Walrand, J.; Pekkala, K.

In: Journal of molecular spectroscopy, Vol. 161, No. 1, 01.09.1993, p. 80-101.

Research output: Contribution to journalArticle

TY - JOUR

T1 - A New Analysis of Rovibrational Bands of Propyne in the 10-, 16-, and 30-μm Regions

AU - Graner, G.

AU - Farrenq, R.

AU - Blanquet, G.

AU - Walrand, J.

AU - Pekkala, K.

N1 - Copyright 2008 Elsevier B.V., All rights reserved.

PY - 1993/9/1

Y1 - 1993/9/1

N2 - After the most prominent bands of propyne (CHCCH) in the region of 9-11, 16, and 30 μm have been analyzed, we have undertaken the study of weaker bands in the same regions. The main purpose of this study is to reach all levels in the 900-1100 cm energy range, in order to make possible a global treatment of all these interacting levels. High-resolution Fourier transform spectra have been used in all three regions and also tunable diode laser spectra in the 16-μm region. The major findings concern the (ν + ν) PAPE band at 10μm, the (ν + ν) - ν and (ν + ν) - ν hot bands at 16 μm, and the (3ν) - (2ν) and (3ν) - (2ν) "superhot hands" at 30 μm. Several local resonances in these bands have also been detected.

AB - After the most prominent bands of propyne (CHCCH) in the region of 9-11, 16, and 30 μm have been analyzed, we have undertaken the study of weaker bands in the same regions. The main purpose of this study is to reach all levels in the 900-1100 cm energy range, in order to make possible a global treatment of all these interacting levels. High-resolution Fourier transform spectra have been used in all three regions and also tunable diode laser spectra in the 16-μm region. The major findings concern the (ν + ν) PAPE band at 10μm, the (ν + ν) - ν and (ν + ν) - ν hot bands at 16 μm, and the (3ν) - (2ν) and (3ν) - (2ν) "superhot hands" at 30 μm. Several local resonances in these bands have also been detected.

UR - http://www.scopus.com/inward/record.url?scp=0001853292&partnerID=8YFLogxK

U2 - 10.1006/jmsp.1993.1217

DO - 10.1006/jmsp.1993.1217

M3 - Article

VL - 161

SP - 80

EP - 101

JO - Journal of molecular spectroscopy

JF - Journal of molecular spectroscopy

SN - 0022-2852

IS - 1

ER -