A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst

Manuel Souto; Andrea Santiago-Portillo; Miguel Palomino; Iñigo J. Vitórica-Yrezábal; Bruno J.C. Vieira; João C. Waerenborgh; Susana Valencia; Sergio Navalón; Fernando Rey; Hermenegildo García; Guillermo Mínguez Espallargas

doi:10.1039/c7sc04829g

A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst

Manuel Souto, Andrea Santiago-Portillo, Miguel Palomino, Iñigo J. Vitórica-Yrezábal, Bruno J.C. Vieira, João C. Waerenborgh, Susana Valencia, Sergio Navalón, Fernando Rey, Hermenegildo García, Guillermo Mínguez Espallargas

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Abstract

Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe₃(μ₃-O)(COO)₆] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.

Original language	English
Pages (from-to)	2413-2418
Number of pages	6
Journal	Chemical Science
Volume	9
Issue number	9
DOIs	https://doi.org/10.1039/c7sc04829g
Publication status	Published - 7 Mar 2018
Externally published	Yes

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Souto, M., Santiago-Portillo, A., Palomino, M., Vitórica-Yrezábal, I. J., Vieira, B. J. C., Waerenborgh, J. C., Valencia, S., Navalón, S., Rey, F., García, H., & Mínguez Espallargas, G. (2018). A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst. Chemical Science, 9(9), 2413-2418. https://doi.org/10.1039/c7sc04829g

@article{6179f37fd2b644afbc1107706801bdd8,

title = "A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst",

abstract = "Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(μ3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.",

author = "Manuel Souto and Andrea Santiago-Portillo and Miguel Palomino and Vit{\'o}rica-Yrez{\'a}bal, {I{\~n}igo J.} and Vieira, {Bruno J.C.} and Waerenborgh, {Jo{\~a}o C.} and Susana Valencia and Sergio Naval{\'o}n and Fernando Rey and Hermenegildo Garc{\'i}a and {M{\'i}nguez Espallargas}, Guillermo",

note = "Funding Information: The work has been supported by the European Union (ERC-2016-CoG 724681-S-CAGE) and the Spanish MINECO (CTQ 2014-59209-P, CTQ2017-89528-P and MAT2015-71842-P). We also thank the Spanish government for the provision of a Severo Ochoa project (SEV-2016-0683) and a Mar{\'i}a de Maeztu project (MDM-2015-0538). G. M. E. and M. S. thank MINECO for a Ram{\'o}n y Cajal and a Juan de la Cierva-Formaci{\'o}n fellowships, respectively. We thank J. M. Mart{\'i}nez-Agudo, G. Agust{\'i}and J. Romero from the University of Valencia for their magnetic and cyclic voltammetry measurements. We thank the Diamond Light Source (UK) for the synchrotron beamtime. C2TN/IST authors acknowledge the Portuguese Foundation for Science and Technology (FCT), contract UID/Multi/04349/2013. Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.",

year = "2018",

month = mar,

day = "7",

doi = "10.1039/c7sc04829g",

language = "English",

volume = "9",

pages = "2413--2418",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

number = "9",

}

Souto, M, Santiago-Portillo, A, Palomino, M, Vitórica-Yrezábal, IJ, Vieira, BJC, Waerenborgh, JC, Valencia, S, Navalón, S, Rey, F, García, H & Mínguez Espallargas, G 2018, 'A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst', Chemical Science, vol. 9, no. 9, pp. 2413-2418. https://doi.org/10.1039/c7sc04829g

TY - JOUR

T1 - A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst

AU - Souto, Manuel

AU - Santiago-Portillo, Andrea

AU - Palomino, Miguel

AU - Vitórica-Yrezábal, Iñigo J.

AU - Vieira, Bruno J.C.

AU - Waerenborgh, João C.

AU - Valencia, Susana

AU - Navalón, Sergio

AU - Rey, Fernando

AU - García, Hermenegildo

AU - Mínguez Espallargas, Guillermo

N1 - Funding Information: The work has been supported by the European Union (ERC-2016-CoG 724681-S-CAGE) and the Spanish MINECO (CTQ 2014-59209-P, CTQ2017-89528-P and MAT2015-71842-P). We also thank the Spanish government for the provision of a Severo Ochoa project (SEV-2016-0683) and a María de Maeztu project (MDM-2015-0538). G. M. E. and M. S. thank MINECO for a Ramón y Cajal and a Juan de la Cierva-Formación fellowships, respectively. We thank J. M. Martínez-Agudo, G. Agustíand J. Romero from the University of Valencia for their magnetic and cyclic voltammetry measurements. We thank the Diamond Light Source (UK) for the synchrotron beamtime. C2TN/IST authors acknowledge the Portuguese Foundation for Science and Technology (FCT), contract UID/Multi/04349/2013. Publisher Copyright: © 2018 The Royal Society of Chemistry. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.

PY - 2018/3/7

Y1 - 2018/3/7

N2 - Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(μ3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.

AB - Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(μ3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.

UR - http://www.scopus.com/inward/record.url?scp=85042703761&partnerID=8YFLogxK

U2 - 10.1039/c7sc04829g

DO - 10.1039/c7sc04829g

M3 - Article

AN - SCOPUS:85042703761

SN - 2041-6520

VL - 9

SP - 2413

EP - 2418

JO - Chemical Science

JF - Chemical Science

IS - 9

ER -

A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst

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