TY - JOUR
T1 - A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst
AU - Souto, Manuel
AU - Santiago-Portillo, Andrea
AU - Palomino, Miguel
AU - Vitórica-Yrezábal, Iñigo J.
AU - Vieira, Bruno J.C.
AU - Waerenborgh, João C.
AU - Valencia, Susana
AU - Navalón, Sergio
AU - Rey, Fernando
AU - García, Hermenegildo
AU - Mínguez Espallargas, Guillermo
N1 - Funding Information:
The work has been supported by the European Union (ERC-2016-CoG 724681-S-CAGE) and the Spanish MINECO (CTQ 2014-59209-P, CTQ2017-89528-P and MAT2015-71842-P). We also thank the Spanish government for the provision of a Severo Ochoa project (SEV-2016-0683) and a María de Maeztu project (MDM-2015-0538). G. M. E. and M. S. thank MINECO for a Ramón y Cajal and a Juan de la Cierva-Formación fellowships, respectively. We thank J. M. Martínez-Agudo, G. Agustíand J. Romero from the University of Valencia for their magnetic and cyclic voltammetry measurements. We thank the Diamond Light Source (UK) for the synchrotron beamtime. C2TN/IST authors acknowledge the Portuguese Foundation for Science and Technology (FCT), contract UID/Multi/04349/2013.
Publisher Copyright:
© 2018 The Royal Society of Chemistry.
Copyright:
Copyright 2018 Elsevier B.V., All rights reserved.
PY - 2018/3/7
Y1 - 2018/3/7
N2 - Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(μ3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.
AB - Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(μ3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.
UR - http://www.scopus.com/inward/record.url?scp=85042703761&partnerID=8YFLogxK
U2 - 10.1039/c7sc04829g
DO - 10.1039/c7sc04829g
M3 - Article
AN - SCOPUS:85042703761
SN - 2041-6520
VL - 9
SP - 2413
EP - 2418
JO - Chemical Science
JF - Chemical Science
IS - 9
ER -