TY - JOUR
T1 - A dinitrobenzoate derivative of an α-methoxy-γ-hydroxysilane
AU - Baudoux, G.
AU - Norberg, B.
AU - Bousbaa, J.
AU - Krief, A.
AU - Evrard, G.
PY - 1998/12/15
Y1 - 1998/12/15
N2 - The structure of (2S*, 4S*)-4-methoxy-4-phenyl-4-(trimethylsilyl)-2-butyl 3,5-dinitrobenzoate, CHNOSi, is presented and discussed. The compound was synthesized by a stereoselective [1-4] retro-Brook reaction, followed by acylation using 3,5-dinitrobenzoyl chloride. The Si-O chain adopts a sterically hindered conformation resembling a five-membered ring.
AB - The structure of (2S*, 4S*)-4-methoxy-4-phenyl-4-(trimethylsilyl)-2-butyl 3,5-dinitrobenzoate, CHNOSi, is presented and discussed. The compound was synthesized by a stereoselective [1-4] retro-Brook reaction, followed by acylation using 3,5-dinitrobenzoyl chloride. The Si-O chain adopts a sterically hindered conformation resembling a five-membered ring.
UR - http://www.scopus.com/inward/record.url?scp=0242594894&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0242594894
SN - 0108-2701
VL - 54
SP - 1944
EP - 1945
JO - Acta crystallographica. Section C: Crystal structure communications
JF - Acta crystallographica. Section C: Crystal structure communications
IS - 12
ER -