A dinitrobenzoate derivative of an α-methoxy-γ-hydroxysilane

G. Baudoux, B. Norberg, J. Bousbaa, A. Krief, G. Evrard

Research output: Contribution to journalArticle

Abstract

The structure of (2S*, 4S*)-4-methoxy-4-phenyl-4-(trimethylsilyl)-2-butyl 3,5-dinitrobenzoate, CHNOSi, is presented and discussed. The compound was synthesized by a stereoselective [1-4] retro-Brook reaction, followed by acylation using 3,5-dinitrobenzoyl chloride. The Si-O chain adopts a sterically hindered conformation resembling a five-membered ring.
Original languageEnglish
Pages (from-to)1944-1945
Number of pages2
JournalActa crystallographica Section C: Crystal Structure communications
Volume54
Issue number12
Publication statusPublished - 15 Dec 1998

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Acylation
Conformations
Derivatives
3,5-dinitrobenzoyl chloride
3,5-dinitrobenzoic acid

Cite this

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abstract = "The structure of (2S*, 4S*)-4-methoxy-4-phenyl-4-(trimethylsilyl)-2-butyl 3,5-dinitrobenzoate, CHNOSi, is presented and discussed. The compound was synthesized by a stereoselective [1-4] retro-Brook reaction, followed by acylation using 3,5-dinitrobenzoyl chloride. The Si-O chain adopts a sterically hindered conformation resembling a five-membered ring.",
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A dinitrobenzoate derivative of an α-methoxy-γ-hydroxysilane. / Baudoux, G.; Norberg, B.; Bousbaa, J.; Krief, A.; Evrard, G.

In: Acta crystallographica Section C: Crystal Structure communications, Vol. 54, No. 12, 15.12.1998, p. 1944-1945.

Research output: Contribution to journalArticle

TY - JOUR

T1 - A dinitrobenzoate derivative of an α-methoxy-γ-hydroxysilane

AU - Baudoux, G.

AU - Norberg, B.

AU - Bousbaa, J.

AU - Krief, A.

AU - Evrard, G.

PY - 1998/12/15

Y1 - 1998/12/15

N2 - The structure of (2S*, 4S*)-4-methoxy-4-phenyl-4-(trimethylsilyl)-2-butyl 3,5-dinitrobenzoate, CHNOSi, is presented and discussed. The compound was synthesized by a stereoselective [1-4] retro-Brook reaction, followed by acylation using 3,5-dinitrobenzoyl chloride. The Si-O chain adopts a sterically hindered conformation resembling a five-membered ring.

AB - The structure of (2S*, 4S*)-4-methoxy-4-phenyl-4-(trimethylsilyl)-2-butyl 3,5-dinitrobenzoate, CHNOSi, is presented and discussed. The compound was synthesized by a stereoselective [1-4] retro-Brook reaction, followed by acylation using 3,5-dinitrobenzoyl chloride. The Si-O chain adopts a sterically hindered conformation resembling a five-membered ring.

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M3 - Article

AN - SCOPUS:0242594894

VL - 54

SP - 1944

EP - 1945

JO - Acta crystallographica Section C: Crystal Structure communications

JF - Acta crystallographica Section C: Crystal Structure communications

SN - 0108-2701

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ER -