The structure of (2S*, 4S*)-4-methoxy-4-phenyl-4-(trimethylsilyl)-2-butyl 3,5-dinitrobenzoate, CHNOSi, is presented and discussed. The compound was synthesized by a stereoselective [1-4] retro-Brook reaction, followed by acylation using 3,5-dinitrobenzoyl chloride. The Si-O chain adopts a sterically hindered conformation resembling a five-membered ring.
|Number of pages||2|
|Journal||Acta crystallographica Section C: Crystal Structure communications|
|Publication status||Published - 15 Dec 1998|
Baudoux, G., Norberg, B., Bousbaa, J., Krief, A., & Evrard, G. (1998). A dinitrobenzoate derivative of an α-methoxy-γ-hydroxysilane. Acta crystallographica Section C: Crystal Structure communications, 54(12), 1944-1945.