TY - JOUR
T1 - 5-[(E)-Methoxy(phenyl)methylidene]-1,3,4-triphenyl-4,5-dihydro-1H-1,2, 4-triazole
AU - Maji, Biplab
AU - Berionni, Guillaume
AU - Mayr, Herbert
AU - Mayer, Peter
PY - 2012/12
Y1 - 2012/12
N2 - In the title compound, C28H23N3O, the 1,2,4-triazole ring deviates slightly from planarity adopting a N3 T C2 conformation which is distorted towards an E C2 conformation. The plane around the ethylene unit makes a dihedral angle of 17.32 (11)°with the mean plane [r.m.s. deviation = 0.036 (1) Å] of the 1,2,4-triazole fragment. The dihedral angles between the four phenyl rings and the 1,2,4-triazole ring are 31.01 (10), 49.01 (8), 78.55 (6) and 41.51 (9)°. In the crystal, molecules are linked along [100] by weak C-H⋯O hydrogen bonds.
AB - In the title compound, C28H23N3O, the 1,2,4-triazole ring deviates slightly from planarity adopting a N3 T C2 conformation which is distorted towards an E C2 conformation. The plane around the ethylene unit makes a dihedral angle of 17.32 (11)°with the mean plane [r.m.s. deviation = 0.036 (1) Å] of the 1,2,4-triazole fragment. The dihedral angles between the four phenyl rings and the 1,2,4-triazole ring are 31.01 (10), 49.01 (8), 78.55 (6) and 41.51 (9)°. In the crystal, molecules are linked along [100] by weak C-H⋯O hydrogen bonds.
KW - data-to-parameter ratio = 13.1
KW - mean ω(C-C) = 0.003 Å
KW - R factor = 0.045
KW - single-crystal X-ray study
KW - T = 200 K
KW - wR factor = 0.116
UR - http://www.scopus.com/inward/record.url?scp=84870862889&partnerID=8YFLogxK
U2 - 10.1107/S1600536812045692
DO - 10.1107/S1600536812045692
M3 - Article
AN - SCOPUS:84870862889
SN - 1600-5368
VL - 68
JO - Acta crystallographica. Section E: Structure reports
JF - Acta crystallographica. Section E: Structure reports
IS - 12
ER -