Abstract
A series of supported cobalt-based nanocatalysts were synthesized by a one-step self-reduction method using cobalt-based organic framework as precursor. The effect of self-reduction of carbonization on the catalytic performance of supported cobalt-based catalysts was studied. This method successfully controlled the hierarchically porous structure of supports and the size of cobalt nanoparticles. The prepared Co-based catalysts had high catalytic activity and product selectivity for selective hydrogenation of 1,3-butadiene. Specially, it was found that the catalyst carbonized at 600℃ contained a hierarchically porous structure with large surface area, and a uniform distribution of cobalt nanoparticles without obvious aggregation. Most importantly, the corresponding sample exhibited a rather low 100% conversion temperature at 60℃ for selective hydrogenation of 1,3-butadiene, but with butenes selectivity as high as 61%. This work provides a new strategy for the preparation of supported non-noble metal catalysts with high-performance for hydrogenation reactions.
Translated title of the contribution | Self-reduction for the Synthesis of Co Supported on Hierarchically Porous Carbon for Selective Hydrogenation Reaction |
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Original language | Chinese |
Pages (from-to) | 639-645 |
Number of pages | 7 |
Journal | Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities |
Volume | 41 |
Issue number | 4 |
DOIs | |
Publication status | Published - 10 Apr 2020 |
Keywords
- Catalyst
- Hierarchically porous structure
- Metal organic framework
- Non-noble metal
- Selective hydrogenation
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Physical Chemistry and characterization(PC2)
Johan Wouters (Manager) & Carmela Aprile (Manager)
Technological Platform Physical Chemistry and characterizationFacility/equipment: Technological Platform