Stability of carbonyl complexes (CC) of alkali and transition metals is studied by quantum mechanics methods with respect to the vibrational excitation of the CO molecule. Interaction between the relatively close excited electronic states of CC transition metals and the excited vibrational states of CO is verified as a reason of the CO elimination from the CC.
|Effective start/end date||1/09/01 → 31/12/04|
- alkali-carbonyl complexes
- CO dissociation
- carbonyl-transition metals complexes
- excited states
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