Chemistry Department &ndash; Research Output

2020

Complex mineralogical-geochemical sequences and weathering events in the supergene ore of the Cu–Co Luiswishi deposit (Katanga, D.R. Congo)

Fontaine, L., De Putter, T., Bernard, A., Decrée, S., Cailteux, J., Wouters, J. & Yans, J., Jan 2020, In : Journal of African Earth Sciences. 161, 103674.

Research output: Contribution to journal › Article

weathering

sulfide

malachite

saprolite

copper

Hollow nitrogen-doped carbon/sulfur@MnO₂ nanocomposite with structural and chemical dual-encapsulation for lithium-sulfur battery

Chen, H., Dong, W. D., Xia, F. J., Zhang, Y. J., Yan, M., Song, J. P., Zou, W., Liu, Y., Hu, Z. Y., Liu, J., Li, Y., Wang, H. E., Chen, L. H. & Su, B. L., 1 Feb 2020, In : Chemical Engineering Journal. 381, 122746.

Research output: Contribution to journal › Article

encapsulation

lithium

Encapsulation

Sulfur

Nanocomposites

Using ammonia for reactive magnetron sputtering, a possible alternative to HiPIMS?

Rassinfosse, L., Colaux, J. L., Pilloud, D., Nominé, A., Tumanov, N., Lucas, S., Pireaux, J. J. & Haye, E., 1 Feb 2020, In : Applied Surface Science. 502, 144176.

Research output: Contribution to journal › Article

Reactive sputtering

Ammonia

Magnetron sputtering

ammonia

magnetron sputtering

2019

3D Graphene-based macro-mesoporous frameworks as enzymatic electrodes

Shen, L., Ying, J., Ren, L., Yao, Y., Lu, Y., Dong, Y., Tian, G., Yang, X. Y. & Su, B. L., 1 Jul 2019, In : Journal of Physics and Chemistry of Solids. 130, p. 1-5 5 p.

Research output: Contribution to journal › Article

Graphite

Graphene

Macros

graphene

Electrodes

Acido-triggered switching of the second-order nonlinear optical properties of a ferrocenyl-containing indolino-oxazolidine derivative

PIELAK, K., Bondu, F., Sanguinet, L., Rodriguez, V., Castet, F. & Champagne, B., 1 Jan 2019, In : Dyes and pigments. 160, p. 641-646 6 p.

Research output: Contribution to journal › Article

Optical properties

Derivatives

Rayleigh scattering

Excited states

Charge transfer

Acid-responsive H ₂ -releasing Fe nanoparticles for safe and effective cancer therapy

Kou, Z., Zhao, P., Wang, Z., Jin, Z., Chen, L., Su, B. L. & He, Q., 1 Jan 2019, In : Journal Of Materials Chemistry B. 7, 17, p. 2759-2765 7 p.

Research output: Contribution to journal › Article

Carboxymethylcellulose Sodium

Hydrogen

Tumors

Nanoparticles

Cellulose

A coloring tool for spiropyrans: Solid state metal-organic complexation: Versus salification

Seiler, V. K., Robeyns, K., Tumanov, N., Cinčić, D., Wouters, J., Champagne, B. & Leyssens, T., 10 Jul 2019, In : CrystEngComm. 21, 33, p. 4925-4933 9 p.

Research output: Contribution to journal › Article

Coloring

Complexation

Metals

solid state

metals

All-polymer solar cells based on photostable bis(perylene diimide) acceptor polymers

Lenaerts, R., Cardeynaels, T., Sudakov, I., Kesters, J., Verstappen, P., Manca, J., Champagne, B., Lutsen, L., Vanderzande, D., Vandewal, K., Goovaerts, E. & Maes, W., 1 Jul 2019, In : Solar Energy Materials and Solar Cells. 196, p. 178-184 7 p.

Research output: Contribution to journal › Article

Perylene

Polymers

Thiophenes

Electrons

Thiophene

Anti-alcohol abuse drug disulfiram inhibits human PHGDH via disruption of its active tetrameric form through a specific cysteine oxidation

Spillier, Q., Vertommen, D., Ravez, S., Marteau, R., Thémans, Q., Corbet, C., Feron, O., Wouters, J. & Frédérick, R., 1 Dec 2019, In : Scientific Reports. 9, 1, 4737.

Research output: Contribution to journal › Article

Open Access

Phosphoglycerate Dehydrogenase

Disulfiram

Alcoholism

Cysteine

Pharmaceutical Preparations

1 Downloads (Pure)

A Simple and Efficient Mechanochemical Route for the Synthesis of Salophen Ligands and of the Corresponding Zn, Ni, and Pd Complexes

Fusaro, L., Carletta, A., Dubois, J., Tumanov, N., Aprile, C., Wouters, J., Dalla Cort, A. & Leoni, L., 1 Jan 2019, In : Molecules. 24, 12, p. 2314 11 p., 2314.

Research output: Contribution to journal › Article

Open Access

File

X-Ray Diffraction

routes

Ligands

solid state

ligands

A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

Mahmoudi, H., Valentini, F., Ferlin, F., Bivona, L. A., Anastasiou, I., Fusaro, L., Aprile, C., Marrocchi, A. & Vaccaro, L., 2019, In : Green Chemistry. 21, 2, p. 355-360 6 p.

Research output: Contribution to journal › Article

Polystyrenes

palladium

Palladium

Binding sites

Leaching

2 Downloads (Pure)

Carbon paste modified with Bi decorated multi-walled carbon nanotubes and CTAB as a sensitive voltammetric sensor for the detection of Caffeic acid

Erady, V., Mascarenhas, R. J., Satpati, A. K., Bhakta, A. K., Mekhalif, Z., Delhalle, J. & Dhason, A., 1 May 2019, In : Microchemical Journal. 146, p. 73-82 10 p.

Research output: Contribution to journal › Article

Carbon Nanotubes

Ointments

Carbon

Sensors

Voltammetry

Cascade electronic band structured zinc oxide/bismuth vanadate/three-dimensional ordered macroporous titanium dioxide ternary nanocomposites for enhanced visible light photocatalysis

Zhao, H., Zalfani, M., Li, C. F., Liu, J., Hu, Z. Y., Mahdouani, M., Bourguiga, R., Li, Y. & Su, B. L., 15 Mar 2019, In : Journal of Colloid and Interface Science. 539, p. 585-597 13 p.

Research output: Contribution to journal › Article

Zinc Oxide

Photocatalysis

Zinc oxide

Bismuth

Titanium dioxide

Complementary Synthetic Approaches toward 9-Phosphatriptycene and Structure-Reactivity Investigations of Its Association with Sterically Hindered Lewis Acids

Hu, L., Mahaut, D., Tumanov, N., Wouters, J., Robiette, R. & Berionni, G., 6 Sep 2019, In : Journal of Organic Chemistry. 84, 17, p. 11268-11274 7 p.

Research output: Contribution to journal › Article

Lewis Acids

Carbon

Boron

Cyclization

Alkalinity

Copper-zinc alloy electrodeposition mediated by triethanolamine as a complexing additive and chemical dealloying

Vivegnis, S., Delhalle, J., Mekhalif, Z. & Renner, F., 1 Oct 2019, In : Electrochimica Acta. 319, p. 400-409 10 p.

Research output: Contribution to journal › Article

Triethanolamine

Zinc alloys

Copper alloys

Electrodeposition

Copper

Coupled cluster investigation of the vibrational and electronic second and third harmonic scattering hyperpolarizabilities of the water molecule

Beaujean, P. & Champagne, B., 14 Aug 2019, In : The journal of chemical physics. 151, 6, 11 p., 064303.

Research output: Contribution to journal › Article

Open Access

Scattering

harmonics

Molecules

Water

scattering

Crossed 2D versus Slipped 1D π-Stacking in Polymorphs of Crystalline Organic Thin Films: Impact on the Electronic and Optical Response

Aliaga-Gosalvez, M. J., Demitri, N., Dohr, M., Roldao, J. C., Park, S. K., Oh, S., Varghese, S., Park, S. Y., Olivier, Y., Milián-Medina, B., Resel, R. & Gierschner, J., 1 Nov 2019, In : Advanced Optical Materials. 7, 21, 1900749.

Research output: Contribution to journal › Article

Crystallization

Polymorphism

Spontaneous emission

Crystalline materials

Thin films

Crystal structures and snapshots along the reaction pathway of human phosphoserine phosphatase

Haufroid, M., Mirgaux, M., Leherte, L. & Wouters, J., 1 Jun 2019, In : Acta Crystallographica Section D: Biological Crystallography. 75, p. 592-604 13 p.

Research output: Contribution to journal › Article

Serine

Enzymes

Phosphoserine

Molecular Dynamics Simulation

Glycine

Design and Catalytic Applications of 1D tubular nanostructures: Improving Efficiency in Glycerol Conversion

Bivona, L., Vivian, A., Fusaro, L., Fiorilli, S. & Aprile, C., 15 Jun 2019, In : Applied Catalysis B Environmental. 247, p. 182-190 9 p.

Research output: Contribution to journal › Article

Glycerol

Nanotubes

Nanostructures

Silicon Dioxide

silica

Design and synthesis of a new soluble natural β-carboline derivative for preclinical study by intravenous injection

Marx, S., Bodart, L., Tumanov, N. & Wouters, J., 25 Mar 2019, In : International Journal of Molecular Sciences. 20, 6, 14 p., 1491.

Research output: Contribution to journal › Article

Open Access

Carbolines

Intravenous Injections

Solubility

multiple docking adapters

solubility

Efficient Conversion of Carbon Dioxide by Imidazolium-Based Cross-Linked Nanostructures Containing Polyhedral Oligomeric Silsesquioxane (POSS) Building Blocks

Calabrese, C., Fusaro, L., Liotta, L. F., Giacalone, F., Comès, A., Campisciano, V., Aprile, C. & Gruttadauria, M., 1 Oct 2019, In : ChemPlusChem. 84, 10, p. 1536-1543 8 p.

Research output: Contribution to journal › Article

glycidol

Carbonates

Carbon Dioxide

Nanostructures

Productivity

Electrografting of mixed organophosphonic monolayers for SI-ATRP of 2-methacryloyloxyethyl phosphorylcholine

Arrotin, B., Noël, J. M., Delhalle, J., Mespouille, L. & Mekhalif, Z., 15 Jul 2019, In : Journal of Coatings Technology and Research. 16, 4, p. 1121-1132 12 p.

Research output: Contribution to journal › Article

Atom transfer radical polymerization

Monolayers

Self assembled monolayers

polymerization

acids

Fabrication of Large Area Crack-Free 2D and 3D WO ₃ Inverse Opal Films by “Dynamic Hard Template Infiltration Strategy”

Li, H., Li, S., Robichaud, J., Su, B. L. & Djaoued, Y., 22 Mar 2019, In : ChemistrySelect. 4, 11, p. 3266-3273 8 p.

Research output: Contribution to journal › Article

Infiltration

Cracks

Fabrication

Electrochromic devices

Composite films

Fingerprint of Aromaticity and Molecular Topology on the Photophysical Properties of Octaphyrins

Woller, T., Geerlings, P., Proft, F. D., Champagne, B. & Alonso, M., 28 Mar 2019, In : Journal of Physical Chemistry C. 123, 12, p. 7318-7335 18 p.

Research output: Contribution to journal › Article

topology

Porphyrins

Topology

conjugation

porphyrins

First Principles Investigation of the Polarisability and First Hyperpolarizability of Anhydride Derivatives

Champagne, B. & Hadji, D., 2019, In : Chemistry Africa . 2, p. 443-453 11 p.

Research output: Contribution to journal › Article

Open Access

Anhydrides

Dipole moment

Derivatives

Anisotropy

Maleic Anhydrides

Fluoride binding by an anionic receptor: tuning the acidity of amide NH groups for basic anion hydrogen bonding and recognition

Caltagirone, C., Montis, R., Lippolis, V., Bencini, A., Conti, L., Giorgi, C., Horton, P., Coles, S., Mapp, L. K., Gale, P. A. & Fusaro, L., 1 Jan 2019, In : Chem. commun.. 55, 19, p. 2745-2748 4 p.

Research output: Contribution to journal › Article

Fluorides

Amides

Acidity

Anions

Hydrogen bonds

HgII-Mediated TlI-to-TlIII Oxidation in Dynamic PbII/Tl Porphyrin Complexes

Le Gac, S., Ndoyom, V., Fusaro, L., Dorcet, V. & Boitrel, B., 14 Jan 2019, In : Chemistry: A European Journal. 25, 3, p. 845-853 9 p.

Research output: Contribution to journal › Article

Porphyrins

Metal ions

Thallium

Oxidation

Salts

Identifying, Characterizing, and Understanding Nefiracetam in Its Solid State Forms: A Potential Antidementia Drug

Buol, X., Robeyns, K., Tumanov, N., Wouters, J. & Leyssens, T., 1 Nov 2019, In : Journal of Pharmaceutical Sciences. 108, 11, p. 3616-3622 7 p.

Research output: Contribution to journal › Article

Nootropic Agents

Thermodynamics

Solubility

Pharmaceutical Preparations

nefiracetam

In-Situ Growing Mesoporous CuO/O-Doped g-C₃N₄ Nanospheres for Highly Enhanced Lithium Storage

Mohamed, H. S. H., Wu, L., Li, C. F., Hu, Z. Y., Liu, J., Deng, Z., Chen, L. H., Li, Y. & Su, B. L., 11 Sep 2019, In : ACS Applied Materials and Interfaces. 11, 36, p. 32957-32968 12 p.

Research output: Contribution to journal › Article

Nanospheres

Lithium

Anodes

Current density

Oxides

Interaction of POPC, DPPC, and POPE with the μ opioid receptor: A coarse-grained molecular dynamics study

Angladon, M-A., Fossépré, M., Leherte, L. & Vercauteren, D., 1 Mar 2019, In : PLoS ONE. 14, 3, p. e0213646 19 p., e0213646.

Research output: Contribution to journal › Article

Open Access

molecular dynamics

narcotics

Opioid Receptors

Molecular Dynamics Simulation

Molecular dynamics

Macrocellular Titanosilicate Monoliths as Highly Efficient Structured Olefin Epoxidation Catalysts

Smeets, V., van den Biggelaar, L., Barakat, T., Gaigneaux, E. M. & Debecker, D. P., 20 Mar 2019, In : ChemCatChem. 11, 6, p. 1593-1597 5 p.

Research output: Contribution to journal › Article

epoxidation

Epoxidation

Alkenes

Emulsions

alkenes

Magnetically-induced current density investigation in carbohelicenes and azahelicenes

Cherni, E., Champagne, B., Ayadi, S. & Liégeois, V., 1 Jan 2019, In : Physical Chemistry Chemical Physics. 21, 27, p. 14678-14691 14 p.

Research output: Contribution to journal › Article

Induced currents

Benzene

Current density

Pyrroles

current density

Mercaptosilane-Passivated CuInS₂ Quantum Dots for Luminescence Thermometry and Luminescent Labels

Marin, R., Vivian, A., Skripka, A., Migliori, A., Morandi, V., Enrichi, F., Vetrone, F., Ceroni, P., Aprile, C. & Canton, P., 26 Apr 2019, In : ACS Applied Nano Materials. 2, 4, p. 2426-2436 11 p.

Research output: Contribution to journal › Article

Semiconductor quantum dots

Luminescence

Labels

Solid state devices

Silanes

MOF-derived nitrogen-doped core-shell hierarchical porous carbon confining selenium for advanced lithium-selenium batteries

Song, J. P., Wu, L., Dong, W. D., Li, C., Chen, L. H., Dai, X., Li, C., Chen, H., Zou, W., Yu, W. B., Hu, Z. Y., Liu, J., Wang, H. E., Li, Y. & Su, B. L., 14 Apr 2019, In : Nanoscale. 11, 14, p. 6970-6981 12 p.

Research output: Contribution to journal › Article

Selenium

Lithium

Nitrogen

Carbon

Metals

Molecular cloning and 3D model of a fatty-acid elongase in a carnivorous freshwater teleost, the European perch (Perca fluviatilis)

Tinti, E., Geay, F., Lopes Rodrigues, M., Kestemont, P., Perpète, E. & Michaux, C., 1 Jun 2019, In : 3 Biotech. 9, 6, p. 242 14 p., 242.

Research output: Contribution to journal › Article

Perca fluviatilis

highly unsaturated fatty acids

molecular cloning

endoplasmic reticulum

fatty acids

Molecular Recognition of Strong Acids by Using a 2-Ureido-4-Ferrocenyl Pyrimidine Receptor

Keszei, S. J., Balogh, S., Fehér, C., Nagy, L., Tumanov, N., Wouters, J., Lendvay, G. & Skoda-Földes, R., 17 Oct 2019, In : European Journal of Inorganic Chemistry. 2019, 38, p. 4095-4104 10 p.

Research output: Contribution to journal › Article

Open Access

Molecular recognition

Anions

Acids

Nuclear magnetic resonance

Trifluoroacetic Acid

Molybdenum disulfide quantum dots directing zinc indium sulfide heterostructures for enhanced visible light hydrogen production

Liu, Y., Li, C. F., Li, X. Y., Yu, W. B., Dong, W. D., Zhao, H., Hu, Z. Y., Deng, Z., Wang, C., Wu, S. J., Chen, H., Liu, J., Wang, Z., Chen, L. H., Li, Y. & Su, B. L., 1 Sep 2019, In : Journal of Colloid and Interface Science. 551, p. 111-118 8 p.

Research output: Contribution to journal › Article

Open Access

Indium sulfide

Hydrogen production

Semiconductor quantum dots

Molybdenum

Heterojunctions

Multiple Charge Transfer States in Donor–Acceptor Heterojunctions with Large Frontier Orbital Energy Offsets

Khan, S-U-Z., Londi, G., Liu, X., Fusella, M. A., D’Avino, G., Muccioli, L., Brigeman, A. N., Niesen, B., Yang, T. C-J., Olivier, Y., Dull, J. T., Giebink, N. C., Beljonne, D. & Rand, B. P., 10 Sep 2019, In : Chemistry of Materials. 31, 17, p. 6808-6817 10 p.

Research output: Contribution to journal › Article

Heterojunctions

Charge transfer

Energy gap

Diamines

Open circuit voltage

New Insights into Photochromic Properties of N-Salicylideneaniline Derivatives Using a Cocrystal Engineering Approach

Mercier, G. M., Robeyns, K., Tumanov, N., Champagne, B., Wouters, J. & Leyssens, T., 2 Oct 2019, In : Crystal Growth & Design. 19, 10, p. 5544-5556 13 p.

Research output: Contribution to journal › Article

Open Access

Drawing (graphics)

Benzene Derivatives

Crystal engineering

Photochromism

Imines

Nitrogen-doped graphene in-situ modifying MnO nanoparticles for highly improved lithium storage

Huang, H. W., Fan, S. S., Dong, W., Zou, W., Yan, M., Deng, Z., Zheng, X., Liu, J., Wang, H. E., Chen, L., Li, Y. & Su, B. L., 15 Apr 2019, In : Applied Surface Science. 473, p. 893-901 9 p.

Research output: Contribution to journal › Article

Graphite

Lithium

Graphene

graphene

Nitrogen

Nonlinear Optical Contrast in Azobenzene-Based Self-assembled Monolayers

Tonnelé, C., Champagne, B., Muccioli, L. & Castet, F., 10 Sep 2019, In : Chemistry of Materials. 31, 17, p. 6759-6769 11 p.

Research output: Contribution to journal › Article

Open Access

Azobenzene

Self assembled monolayers

Chromophores

Photoisomerization

Discrete Fourier transforms

Occurrence and repair of alkylating stress in the intracellular pathogen Brucella abortus

Poncin, K., Roba, A., Jimmidi, R., Potemberg, G., Fioravanti, A., Francis, N., Willemart, K., Zeippen, N., Machelart, A., Biondi, E. G., Muraille, E., Vincent, S. P. & De Bolle, X., 24 Oct 2019, In : Nature Communications. 10, 1, p. 4847 4847.

Research output: Contribution to journal › Article

Open Access

File

Brucella abortus

pathogens

Pathogens

Repair

occurrences

Periodic DFT Study of the Effects of Co‐Crystallization on a N‐Salicylideneaniline Molecular Switch

Quertinmont, J., Leyssens, T., Wouters, J. & Champagne, B., 2 Oct 2019, ChemPhysChem, 20, 19, p. 2434-2442 9 p.

Research output: Contribution to specialist publication › Article

Discrete Fourier transforms

Hydrogen bonds

Switches

Halogens

Wave functions

Polymer-Supported Bis-1,2,4-triazolium Ionic Tag Framework for an Efficient Pd(0) Catalytic System in Biomass Derived γ-Valerolactone

Valentini, F., Mahmoudi, H., Bivona, L. A., Piermatti, O., Bagherzadeh, M., Fusaro, L., Aprile, C., Marrocchi, A. & Vaccaro, L., 1 Apr 2019, In : ACS Sustainable Chemistry and Engineering. 7, 7, p. 6939-6946 8 p.

Research output: Contribution to journal › Article

palladium

Palladium

Polymers

Biomass

polymer

Potentialization of anticancer agents by identification of new chemosensitizers active under hypoxia

Marx, S., Van Gysel, M., Breuer, A., Dal Maso, T., Michiels, C., Wouters, J. & Le Calve, B., 2019, In : Biochemical Pharmacology. 162, p. 224-236 13 p.

Research output: Contribution to journal › Article

Probing alkylsilane molecular structure on amorphous silica surfaces by sum frequency generation vibrational spectroscopy: First-principles calculations

Tetsassi Feugmo, C. G., Liégeois, V., Caudano, Y., Cecchet, F. & Champagne, B., 21 Feb 2019, In : The journal of chemical physics. 150, 7, p. 074703 074703.

Research output: Contribution to journal › Article

Probing and suppressing voltage fade of Li-rich Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ cathode material for lithium-ion battery

Zou, W., Xia, F. J., Song, J. P., Wu, L., Chen, L. D., Chen, H., Liu, Y., Dong, W. D., Wu, S. J., Hu, Z. Y., Liu, J., Wang, H. E., Chen, L. H., Li, Y., Peng, D. L. & Su, B. L., 20 Sep 2019, In : Electrochimica Acta. 318, p. 875-882 8 p.

Research output: Contribution to journal › Article

Cathodes

Electric potential

Cations

Positive ions

Lithium-ion batteries

Pushing the Lewis Acidity Boundaries of Boron Compounds With Non‐Planar Triarylboranes Derived from Triptycenes

Ben Saida, A., Chardon, A., Osi, A., Tumanov, N., Wouters, J., Adjieufack, A. I., Champagne, B. & Berionni, G., 18 Nov 2019, In : Angewandte Chemie International Edition. 58, 47, p. 16889-16893 5 p.

Research output: Contribution to journal › Article

Open Access

Boron Compounds

Boron compounds

Boron

Acidity

Lewis Acids

QCM sensing of multivalent interactions between lectins and well-defined glycosylated nanoplatforms

Abellán-Flos, M., Timmer, B. J. J., Altun, S., Aastrup, T., Vincent, S. P. & Ramström, O., 15 Aug 2019, In : Biosensors and Bioelectronics. 139, 111328.

Research output: Contribution to journal › Article

Quartz Crystal Microbalance Techniques

Nanostructures

Quartz crystal microbalances

Lectins

Fullerenes

Radiative and non radiative recombinations study in the novel nanocomposites BiVO ₄ /3DOM-TiO ₂ , ZnO/3DOM-TiO ₂ and BiVO ₄ /3DOM-ZnO: Application to the photocatalysis

Mahdouani, M., Zalfani, M., Bourguiga, R. & Su, B. L., 1 Apr 2019, In : Physica E: Low-Dimensional Systems and Nanostructures. 108, p. 269-280 12 p.

Research output: Contribution to journal › Article

Photocatalysis

radiative recombination

charge carriers

Nanostructures

Nanocomposites